SnTe nanoparticles physicochemically encapsulated by double carbon as conversion-alloying anode materials for superior potassium-ion batteries

Telluride tin (SnTe) is a promising conversion-alloying anode for potassium-ion batteries (PIBs) due to its high theoretical specific capacity induced by multi-electron transport reaction and low operating voltage, whereas huge volume expansion and poor kinetics behavior become key scientific bottleneck limiting the battery performances. Herein, SnTe nanoparticles physicochemically wrapped by graphene and nitrogen -doped carbon (SnTe@rGO@NC) are proposed as anode materials for PIBs. The pre-electrostatic interaction urges the formation of Sn-C and Te-C chemical bonds between SnTe and double carbon to strengthen the interfacial stability and electron transfer, and the conductive architecture with hierarchical encapsulation effect is beneficial to maintaining the electrode integrity and electrochemical dynamics. It is demon-strated from first principles calculations and experimental results that SnTe@rGO@NC contributes fast electron transmission, strong K-ion adsorption, and superior K-ion diffusion capability. Ex-situ characteri-zations uncover that SnTe undergoes conversion-alloying dual-mechanism with the products of K2Te and K4Sn23 replied on Sn redox site (23SnTe + 50K + + 50e - <-> K4Sn23 + 23K2Te). Thus, the SnTe@rGO@NC electrode delivers a high initial charge specific capacity of 243.9 mAh g -1 at 50 mA g -1 , superior rate performance (112.6 mAh g -1 at 1.0 A g -1 ), and outstanding cyclic stability at various current densities.(c) 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

SnTe@rGO@NC, formed by wrapping SnTe nanoparticles with graphene and nitrogen-doped carbon, improves the performance of potassium-ion batteries. It exhibits good interfacial stability, electron transmission, and adsorption and diffusion of potassium ions. Experimental results demonstrate its high initial charge capacity, superior rate performance, and outstanding cyclic stability.