Effect of Ti additions on microstructure and mechanical properties of Cu-Cr-Zr alloy

Ti additions in Cu-Cr-Zr alloys are useful for achieving high mechanical properties. In this work, the influence of Ti contents (0.25 wt%, 0.6 wt%, and 1.02 wt%) on the microstructure, mechanical, and elec-trical properties of Cu-Cr-Zr alloys has been investigated experimentally, along with thermodynamic and kinetic calculations. The electrical conductivity decreased but the hardness/strength increased with in-creasing Ti content. The lower electrical conductivity is due to increased electron scattering through the solution of more Ti atoms in the Cu matrix. As for the higher hardness/strength, it is mainly owing to higher dislocation density and finer FCC-Cr precipitates. Furthermore, a model considering the size dis-tributions of precipitates is adopted to calculate precipitation strengthening quantitatively. The calculated yield strengths are consistent with the experimental ones for the alloys. The thermodynamic and kinetic calculations reveal that increasing Ti content can facilitate the nucleation of FCC-Cr but enhance its ac-tivation energy, hence hindering the growth process. The present work study can provide an effective strategy for producing copper alloys with expected performance.& COPY; 2023 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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In this study, the effect of Ti content on the microstructure, mechanical, and electrical properties of Cu-Cr-Zr alloys was investigated. The electrical conductivity decreased with increasing Ti content due to electron scattering. The higher hardness/strength was attributed to higher dislocation density and finer FCC-Cr precipitates. Thermodynamic and kinetic calculations showed that increasing Ti content facilitated the nucleation of FCC-Cr but hindered its growth process.