期刊
CHEMICAL ENGINEERING & TECHNOLOGY
卷 38, 期 9, 页码 1625-1636出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ceat.201400468
关键词
Aniline; Hydrogenation; Nitrobenzene; Pd/Al2O3 catalyst
资金
- Fundacao para a Ciencia e Tecnologia (FCT) [SFRH/BDE/51794/2012]
- Fundação para a Ciência e a Tecnologia [SFRH/BDE/51794/2012] Funding Source: FCT
The catalytic hydrogenation of nitrobenzene (NB) was studied in a three-phase basket reactor with a commercial Pd/Al2O3 sample as catalyst. The kinetic experiments allowed a better understanding of the mechanism behind the formation of aniline (ANL) and by-products, a topic not yet well comprehended. The effect of some operating conditions was studied and the existence of more by-products than mentioned in the literature was stated; specifically, benzene formation was verified. Both the reaction kinetics and selectivity were found to be strongly dependent on the temperature, while the effect of total pressure is not that pronounced. Moreover, the high selectivity of the catalyst used in the present work was proved, and as such the deep hydrogenation of ANL to form by-products only occurs in considerable extension when the NB concentration in the reaction mixture becomes negligible.
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