期刊
CHEMICAL ENGINEERING & TECHNOLOGY
卷 39, 期 1, 页码 66-80出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ceat.201500195
关键词
Flow chemistry; Fluorine; Photoredox catalysis; Trifluoromethylation; Visible light
The unique properties of fluorine resulting from its tremendously high electrone-gativity make it a key player in the quest of enabling new and advanced qualities for chemical compounds and materials. With the advent of fluorinating reagents, a great diversity of synthetic methodologies has been developed to incorporate fluorine or fluorine-containing groups into small molecules with high conversion and selectivity. Especially photochemically catalyzed fluorination reactions proved their potential for the synthesis of fluorine-containing fine chemicals due to their mild reaction conditions. This tutorial review gives an overview of recently published synthesis strategies that use (visible-) light-absorbing catalysts for the activation of fluorinating reagents. A special focus lies on the use of continuous-flow microreactors for photochemically catalyzed fluorination reactions due to the excellent utilization of this reactor equipment for photochemistry.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据