MXene/Graphene modified cellulose aerogel for photo-electro-assisted all-weather cleanup of high-viscous crude oil from spill

The frequent occurrence of oil spills has led to serious environmental pollution and ecological issues. Given the high-viscosity of crude oil, it is essential to develop sorbents with efficient viscosity reduction and sorption capacity in various environmental conditions. Herein, a superhydrophobic carboxymethyl cellulose (CMC) aerogel co-modified by MXene and graphene jointly (M-Mxene/Gr CA) with aligned channels structure was prepared. The aligned channels structure can effectively improve the longitudinal thermal conductivity and reduce the sorption resistance. Through the modification of MXene and graphene, the aerogel realized efficient photo/electro-thermal conversion, thus ensuring its adaption to various working environments. The rapid heat generation can significantly reduce the viscosity of crude oil, achieving rapid recovery. Under one sun illumi-nation (1.0 kW/m2), the surface temperature of M-Mxene/Gr CA can reach 72.6 degrees C and its sorption capability for high-viscous crude oil reaches 18 g/g. Combining photo-thermal and electro-thermal (0.5 kW/m2 and 23 V), the average sorption rate of crude oil can reach 1.3 x 107 g m- 3 s- 1. Finally, we present a continuous sorption system to recover offshore oil spills under the assistance of a pump. This work provides a new option for tackling high-viscous offshore oil spills due to its environmental friendliness and fast sorption capacity.

Automated summary

The frequent occurrence of oil spills has led to serious environmental pollution and ecological issues. In this study, a superhydrophobic aerogel modified with MXene and graphene was developed, which showed efficient photo/electro-thermal conversion and rapid oil sorption capability.