Green ammonia production technologies: A review of practical progress

Review Chemistry, Multidisciplinary

Recent advances in photocatalytic nitrogen fixation and beyond

Yunxia Wei et al.

Summary: This mini review summarizes the recent advances in materials sciences for photocatalytic nitrogen fixation and discusses the research on the synthesis of ammonia and other high-value chemicals.

NANOSCALE (2022)

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Article Chemistry, Multidisciplinary

Achieving+95% Ammonia Purity by Optimizing the Absorption and Desorption Conditions of Supported Metal Halides

Daniel J. Hrtus et al.

Summary: This study focused on using metal halide solid absorbents for ammonia separation, exploring optimal performance under absorption/desorption conditions. The results demonstrate the potential of these salts to replace traditional ammonia synthesis condensation, offering a greener production method and increased efficiency.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Limnology

Nitrogen fixation: A poorly understood process along the freshwater-marine continuum

Amy M. Marcarelli et al.

Summary: Nitrogen fixation is a crucial element of the global nitrogen cycle, but its rates and ecological dynamics in inland and coastal aquatic ecosystems are still largely unknown. This is due to the diversity of these habitats and the traditional belief that nitrogen fixation rates in these ecosystems are low or non-existent.

LIMNOLOGY AND OCEANOGRAPHY LETTERS (2022)

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Review Chemistry, Applied

Ammonia as a green energy carrier: Electrochemical synthesis and direct ammonia fuel cell-a comprehensive review

Bin Wang et al.

Summary: Achieving carbon neutrality by 2050 is an urgent challenge for the world to address climate change. Ammonia, as a promising medium for hydrogen storage, is considered an ideal carbon-free energy carrier. Its critical advantages in long-distance transportation and storage make it a potential solution for hydrogen. This review provides a comprehensive summary of the latest advancements in electrochemical ammonia synthesis and direct ammonia fuel cells, including process mechanisms, material development, and stability issues.

FUEL PROCESSING TECHNOLOGY (2022)

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Article Chemistry, Multidisciplinary

Optimizing Reaction-Absorption Process for Lower Pressure Ammonia Production

Fouzia Hasan Nowrin et al.

Summary: Ammonia separation using metal halide absorbents is a viable option for ammonia production at lower pressure. The study focuses on optimizing the operating parameters of the reaction-absorption process for large-scale processing. The experiments were conducted in different modes to investigate the reaction parameters, absorption conditions, and transient behavior. The results suggest that the recycle flow rate and absorber temperature significantly influence ammonia production rates. Optimized conditions led to a production rate increase of 14 times compared to previous results. The study also demonstrated stable performance of the reaction-absorption process for multiple cycles.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

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Article Chemistry, Physical

An integrated system for ammonia production from renewable hydrogen: A case study

Merve Ozturk et al.

Summary: This study presents an analysis and assessment study of an integrated system for producing ammonia, consisting of a cryogenic air separation unit, polymer electrolyte membrane electrolyzer, and reactor. The system's efficiency is impacted by solar radiation intensity and inlet air conditions, with an increase in solar influx leading to decreased efficiencies. Additionally, the mass flow rate of inlet air significantly affects ammonia production.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Engineering, Environmental

A technological roadmap to the ammonia energy economy: Current state and missing technologies

Natalia Morlane et al.

Summary: Ammonia is recognized as a key energy carrier with potential applications in low-carbon energy storage, transportation, and power generation. Further research and development are needed to fully utilize its advantages and implement it as a building block in the global low-carbon energy landscape.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Chemistry, Physical

Evaluation of a new geothermal based multigenerational plant with primary outputs of hydrogen and ammonia

Yunus Emre Yuksel et al.

Summary: This paper presents a novel integrated energy plant utilizing geothermal resources to produce multiple useful products. Hydrogen, as an energy carrier, is widely used and mixed with nitrogen to produce ammonia. Energy and exergy analyses are conducted to determine the irreversibilities occurring within the system, leading to the findings of energy and exergy efficiencies of the entire plant.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Agricultural Engineering

A novel biomass gasification based cascaded hydrogen and ammonia synthesis system using Stoichiometric and Gibbs reactors

H. Ishaq et al.

Summary: This study proposes a new configuration of biomass gasification based cascaded ammonia synthesis, which includes a biomass gasifier, heat recovery unit, ammonia production unit, etc. The cascaded ammonia synthesis offers high ammonia conversion rates.

BIOMASS & BIOENERGY (2021)

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Article Chemistry, Physical

Exceeding Single-Pass Equilibrium with Integrated Absorption Separation for Ammonia Synthesis Using Renewable Energy-Redefining the Haber-Bosch Loop

Collin Smith et al.

Summary: This study demonstrates a recycle-less integrated process for ammonia synthesis and separation, setting the foundation for green ammonia technology. By utilizing a novel catalyst and absorbent system, the efficiency and stability of the ammonia synthesis reaction can be improved.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

The activation of porous atomic layered MoS2 basal-plane to induce adjacent Mo atom pairs promoting high efficiency electrochemical N2 fixation

Jinwei Chen et al.

Summary: Porous atomic layered 2H-MoS2 (PAL-MoS2) prepared by one-step calcination treatment shows excellent performance in nitrogen reduction reaction, with high Faradic efficiency and significant NH3 yield.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Review Energy & Fuels

Sustainable Ammonia Production Processes

Seyedehhoma Ghavam et al.

Summary: Recent studies have focused on finding environmentally friendly, energy efficient, and economically viable production processes for ammonia synthesis due to its importance in agriculture and potential as an energy carrier. However, the commonly used Haber-Bosch process for ammonia production has high greenhouse gas emissions and energy usage. Sustainable hydrogen production methods like water electrolysis coupled with renewable technologies are being explored, but they require large amounts of pretreated water. A comparative life cycle assessment of various ammonia production methods shows that significant GHG emissions or high volumes of water are still present in these technologies.

FRONTIERS IN ENERGY RESEARCH (2021)

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Review Chemistry, Physical

Solid oxide fuel cell: Decade of progress, future perspectives and challenges

Mandeep Singh et al.

Summary: Fuel cells are becoming increasingly popular as a highly efficient, clean, and sustainable energy conversion source with different types having their own pros and cons. Solid oxide fuel cells (SOFC) are gaining attention for their high efficiency and versatility in utilizing various fuels apart from hydrogen. Recent advancements mainly focus on two types of SOFC stack designs and their implications for medium and large power requirements.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Review Green & Sustainable Science & Technology

A review on ammonia, ammonia-hydrogen and ammonia-methane fuels

Wai Siong Chai et al.

Summary: The combustion of fuels for energy generation is crucial for human activities, but it results in emissions that cause environmental complications and health risks. The replacement of conventional fuels for zero carbon emission is important, with ammonia offering advantages over hydrogen as a carbon-free fuel, but facing challenges such as low burning velocity and high emissions. Therefore, the study of secondary fuels like hydrogen and methane to assist ammonia combustion is essential.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2021)

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Review Green & Sustainable Science & Technology

Development and Recent Progress on Ammonia Synthesis Catalysts for Haber-Bosch Process

John Humphreys et al.

Summary: Ammonia synthesis from nitrogen and hydrogen is a crucial chemical process with the development of efficient catalysts being a key focus. New catalysts are being developed to improve efficiency and sustainability in ammonia production. The continued innovation in catalysts for the Haber-Bosch process is essential for the future of green ammonia production.

ADVANCED ENERGY AND SUSTAINABILITY RESEARCH (2021)

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Article Chemistry, Multidisciplinary

Impact of grid connectivity on cost and location of green ammonia production: Australia as a case study

Nicholas Salmon et al.

Summary: Green ammonia is a promising derivative of hydrogen that can reduce carbon emissions, but requires significant infrastructure for hydrogen and electricity storage. Connecting to the electricity grid can significantly reduce the additional infrastructure costs, especially in regions like Tasmania, providing the best opportunity to take advantage of low prices when they occur.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Can sustainable ammonia synthesis pathways compete with fossil-fuel based Haber-Bosch processes?

Miao Wang et al.

Summary: The article evaluates various stages of transitioning to sustainable ammonia synthesis, comparing economic feasibility and climate impacts of different synthesis methods, and suggesting technological thresholds. Ammonia synthesis driven by renewable energy sources will have cost and environmental advantages, but major advances in performance are still needed.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Energy & Fuels

Techno-economic comparison of green ammonia production processes

Hanfei Zhang et al.

APPLIED ENERGY (2020)

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Review Chemistry, Physical

A Review on Pd Based Catalysts for CO2 Hydrogenation to Methanol: In-Depth Activity and DRIFTS Mechanistic Study

Opeyemi A. Ojelade et al.

CATALYSIS SURVEYS FROM ASIA (2020)

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Article Thermodynamics

A new solar energy system for ammonia production and utilization in fuel cells

O. Siddiqui et al.

ENERGY CONVERSION AND MANAGEMENT (2020)

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Article Chemistry, Physical

Techno-economic analysis and life cycle assessment for electrochemical ammonia production using proton conducting membrane

Jamie R. Gomez et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Physical

Self-supported NbSe2 nanosheet arrays for highly efficient ammonia electrosynthesis under ambient conditions

Yong Wang et al.

JOURNAL OF CATALYSIS (2020)

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Article Chemistry, Physical

Insights into the role of cation vacancy for significantly enhanced electrochemical nitrogen reduction

Xiaohui Yang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Article Nanoscience & Nanotechnology

Transition Metal Aluminum Boride as a New Candidate for Ambient-Condition Electrochemical Ammonia Synthesis

Yang Fu et al.

NANO-MICRO LETTERS (2020)

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Article Chemistry, Physical

Dynamic analysis of a new solar-wind energy-based cascaded system for hydrogen to ammonia

H. Ishaq et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Multidisciplinary

Performance of a Small-Scale Haber Process: A Techno-Economic Analysis

Bosong Lin et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Chemistry, Physical

Electrocatalysts for acidic oxygen evolution reaction: Achievements and perspectives

Zhijie Chen et al.

NANO ENERGY (2020)

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Article Chemistry, Multidisciplinary

Surface defect-abundant one-dimensional graphitic carbon nitride nanorods boost photocatalytic nitrogen fixation

Derek Hao et al.

NEW JOURNAL OF CHEMISTRY (2020)

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Review Materials Science, Multidisciplinary

Proton Exchange Membrane Electrolyzer Modeling for Power Electronics Control: A Short Review

Burin Yodwong et al.

C-JOURNAL OF CARBON RESEARCH (2020)

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Article Chemistry, Physical

Efficient electrochemical N2 fixation by doped-oxygen-induced phosphorus vacancy defects on copper phosphide nanosheets

Meng Jin et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Surface oxidized two-dimensional antimonene nanosheets for electrochemical ammonia synthesis under ambient conditions

Munkhjargal Bat-Erdene et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Energy & Fuels

Techno-Economic Assessment of Solar Hydrogen Production by Means of Thermo-Chemical Cycles

Massimo Moser et al.

ENERGIES (2019)

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Article Chemistry, Multidisciplinary

Biomass Based Sustainable Ammonia Production: Digestion vs Gasification

Antonio Sanchez et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2019)

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Article Chemistry, Multidisciplinary

Highly Efficient and Selective Generation of Ammonia and Hydrogen on a Graphdiyne-Based Catalyst

Lan Hui et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Physical

Optimizing Pd:Zn molar ratio in PdZn/CeO2 for CO2 hydrogenation to methanol

Opeyemi A. Ojelade et al.

APPLIED CATALYSIS A-GENERAL (2019)

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Article Thermodynamics

Design and analysis of a novel solar-wind based integrated energy system utilizing ammonia for energy storage

O. Siddiqui et al.

ENERGY CONVERSION AND MANAGEMENT (2019)

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Article Engineering, Chemical

Sustainable ammonia production through process synthesis and global optimization

C. Doga Demirhan et al.

AICHE JOURNAL (2019)

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Article Chemistry, Multidisciplinary

Beyond the Thermal Equilibrium Limit of Ammonia Synthesis with Dual Temperature Zone Catalyst Powered by Solar Light

Chengliang Mao et al.

CHEM (2019)

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Review Chemistry, Multidisciplinary

Electrocatalytic Reduction of Nitrogen: From Haber-Bosch to Ammonia Artificial Leaf

Antonio Jose Martin et al.

CHEM (2019)

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Article Chemistry, Multidisciplinary

Consequential life cycle assessment of carbon capture and utilization technologies within the chemical industry

Nils Thonemann et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

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Review Chemistry, Physical

Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction

Mengqicio Li et al.

SMALL METHODS (2019)

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Article Chemistry, Physical

Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water

Yu-Chen Hao et al.

NATURE CATALYSIS (2019)

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Review Chemistry, Physical

Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia

Bryan H. R. Suryanto et al.

NATURE CATALYSIS (2019)

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Article Chemistry, Multidisciplinary

Converting Wind Energy to Ammonia at Lower Pressure

Mandi Malmali et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

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Article Chemistry, Physical

Energy-confined solar thermal ammonia synthesis with K/Ru/TiO2-xHx

Chengliang Mao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Techno-economic study of hydrogen production using CSP technology

R. Boudries

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Green & Sustainable Science & Technology

Economic assessment of hydrogen production from solar driven high-temperature steam electrolysis process

Deepak Yadav et al.

JOURNAL OF CLEANER PRODUCTION (2018)

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Article Chemistry, Multidisciplinary

Better Absorbents for Ammonia Separation

Mandi Malmali et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2018)

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Article Chemistry, Physical

Metal-organic framework- derived nitrogen-doped highly disordered carbon for electrochemical ammonia synthesis using N2 and H2O in alkaline electrolytes

Shreya Mukherjee et al.

NANO ENERGY (2018)

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Article Multidisciplinary Sciences

A physical catalyst for the electrolysis of nitrogen to ammonia

Yang Song et al.

SCIENCE ADVANCES (2018)

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Article Chemistry, Multidisciplinary

Energy-Efficient Nitrogen Reduction to Ammonia at Low Overpotential in Aqueous Electrolyte under Ambient Conditions

Dabin Wang et al.

CHEMSUSCHEM (2018)

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Review Thermodynamics

Ammonia for power

A. Valera-Medina et al.

PROGRESS IN ENERGY AND COMBUSTION SCIENCE (2018)

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Article Engineering, Chemical

Green Ammonia: Impact of Renewable Energy Intermittency on Plant Sizing and Levelized Cost of Ammonia

Richard Nayak-Luke et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2018)

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Article Chemistry, Physical

A technical and economical assessment of hydrogen production potential from solar energy in Morocco

Samir Touili et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Chemistry, Physical

Greening Ammonia toward the Solar Ammonia Refinery

Lu Wang et al.

JOULE (2018)

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Article Chemistry, Physical

Ternary intermetallic LaCoSi as a catalyst for N2 activation

Yutong Gong et al.

NATURE CATALYSIS (2018)

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Review Chemistry, Physical

Catalysts for nitrogen reduction to ammonia

Shelby L. Foster et al.

NATURE CATALYSIS (2018)

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Article Chemistry, Physical

International collaboration in the IAEA nuclear hydrogen production program for benchmarking of HEEP

R. S. El-Emam et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

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Article Chemistry, Physical

Exergoeconomic optimization of a new four-step magnesium-chlorine cycle

Hasan Ozcan et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

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Article Chemistry, Physical

Life cycle assessment of nuclear-based hydrogen and ammonia production options: A comparative evaluation

Yusuf Bicer et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

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Review Green & Sustainable Science & Technology

Production costs of the chemical industry in the EU and other countries: Ammonia, methanol and light olefins

Aikaterini Boulamanti et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2017)

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Review Chemistry, Multidisciplinary

Sustainable Ammonia Production from US Offshore Wind Farms: A Techno-Economic Review

Eric R. Morgan et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2017)

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Article Engineering, Chemical

Column absorption for reproducible cyclic separation in small scale ammonia synthesis

Kevin Wagner et al.

AICHE JOURNAL (2017)

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Article Engineering, Chemical

Conceptual Design of Ammonia-Based Energy Storage System: System Design and Time-Invariant Performance

Ganzhou Wang et al.

AICHE JOURNAL (2017)

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Article Engineering, Environmental

CO2 hydrogenation to methanol over Cu/ZrO2 catalysts: Effects of zirconia phases

Thongthai Witoon et al.

CHEMICAL ENGINEERING JOURNAL (2016)

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Article Chemistry, Multidisciplinary

A comparative technoeconomic analysis of renewable hydrogen production using solar energy

Matthew R. Shaner et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

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Article Engineering, Chemical

Ammonia Synthesis at Reduced Pressure via Reactive Separation

Mandi Malmali et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2016)

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Article Chemistry, Physical

Energy and economic analyses of models developed for sustainable hydrogen production from biogas-based electricity and sewage sludge

Aysegul Abusoglu et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

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Article Chemistry, Physical

A techno-economic assessment of large scale wind-hydrogen production with energy storage in Western Canada

Babatunde Olateju et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2016)

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Article Green & Sustainable Science & Technology

Comparative life cycle assessment of various ammonia production methods

Yusuf Bicer et al.

JOURNAL OF CLEANER PRODUCTION (2016)

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Article Multidisciplinary Sciences

Electride support boosts nitrogen dissociation over ruthenium catalyst and shifts the bottleneck in ammonia synthesis

Masaaki Kitano et al.

NATURE COMMUNICATIONS (2015)

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Article Engineering, Chemical

Synthesis of Ammonia from Intermittently Generated Hydrogen

Simon Schulte Beerbuehl et al.

CHEMIE INGENIEUR TECHNIK (2014)

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Article Green & Sustainable Science & Technology

Techno-Economic Assessment of Nonfossil Ammonia Production

Per Tuna et al.

ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY (2014)

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Article Environmental Sciences

The Haber Bosch-harmful algal bloom (HB-HAB) link

Patricia M. Glibert et al.

ENVIRONMENTAL RESEARCH LETTERS (2014)

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Article Chemistry, Multidisciplinary

A facile and versatile method for preparation of colored TiO2 with enhanced solar-driven photocatalytic activity

Huaqiao Tan et al.

NANOSCALE (2014)

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Article Multidisciplinary Sciences

被撤回的出版物: AMMONIA SYNTHESIS Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3 (Retracted article. See vol. 369, pg. 780, 2020)

Stuart Licht et al.

SCIENCE (2014)

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Article Environmental Sciences

The role of nitrogen in climate change and the impacts of nitrogen-climate interactions in the United States: foreword to thematic issue

Emma C. Suddick et al.

BIOGEOCHEMISTRY (2013)

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Article Optics

Thermo-plasmonics: using metallic nanostructures as nano-sources of heat

Guillaume Baffou et al.

LASER & PHOTONICS REVIEWS (2013)

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Article Multidisciplinary Sciences

Synthesis of ammonia directly from air and water at ambient temperature and pressure

Rong Lan et al.

SCIENTIFIC REPORTS (2013)

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Article Green & Sustainable Science & Technology

Study of individual reactions of the sour compression process for the purification of oxyfuel-derived CO2

Laura Torrente-Murciano et al.

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL (2011)

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Editorial Material Multidisciplinary Sciences

Too much of a good thing

Mark A. Sutton et al.

NATURE (2011)

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Article Multidisciplinary Sciences

Global food demand and the sustainable intensification of agriculture

David Tilman et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2011)

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Article Engineering, Chemical

Ammonia synthesis at atmospheric pressure using a reactor with thin solid electrolyte BaCe0.85Y0.15O3-α membrane

W. B. Wang et al.

JOURNAL OF MEMBRANE SCIENCE (2010)

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Review Chemistry, Physical

Plasmonics for extreme light concentration and manipulation

Jon A. Schuller et al.

NATURE MATERIALS (2010)

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Article Chemistry, Physical

Economic comparison of solar hydrogen generation by means of thermochemical cycles and electrolysis

D. Graf et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2008)

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Article Multidisciplinary Sciences

An Earth-system perspective of the global nitrogen cycle

Nicolas Gruber et al.

NATURE (2008)

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Article Chemistry, Physical

Estimates of the price of hydrogen as a medium for wind and solar sources

John O'M. Bockris et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2007)

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Review Chemistry, Multidisciplinary

Generating heat with metal nanoparticles

Alexander O. Govorov et al.

NANO TODAY (2007)

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Article Engineering, Chemical

A high-density ammonia storage/delivery system based on Mg(NH3)6Cl2 for SCR-DeNOx in vehicles

TD Elmoe et al.

CHEMICAL ENGINEERING SCIENCE (2006)

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Article Chemistry, Physical

Ammonia adsorption by MgCl2, CaCl2 and BaCl2 confined to porous alumina: The fixed bed adsorber

VE Sharonov et al.

REACTION KINETICS AND CATALYSIS LETTERS (2005)

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Article Chemistry, Physical

Wustite as a new precursor of industrial ammonia synthesis catalysts

N Pernicone et al.

APPLIED CATALYSIS A-GENERAL (2003)

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Green ammonia production technologies: A review of practical progress

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