期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 35, 页码 7455-7458出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00963d
关键词
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资金
- NSF of China [21271072]
- Program for Professor of Special Appointment (Eastern Scholar) at the Shanghai Institutions of Higher Learning
- Shanghai Pujiang Program [13PJ1401900]
Inspired by the multicopper active site of laccase, which efficiently catalyzes the oxygen reduction reaction (ORR), herein we report a novel bio-inspired ORR catalyst composed of a multinuclear copper complex that was immobilized on the surface of reduced graphene oxide (rGO) via the covalently grafted triazole-dipyridine (TADPy) dinucleating ligand. This rGO-TADPyCu catalyst exhibited high ORR activity and superior long-term stability compared to Pt/C in alkaline media.
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