4.7 Article

Photoelectrochemical CO2 reduction using a Ru(II)-Re(I) multinuclear metal complex on a p-type semiconducting NiO electrode

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 53, 页码 10722-10725

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02403j

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资金

  1. Japan Society for the Promotion of Science (JSPS) [24107005]
  2. Toyota Motor Corporation
  3. Grants-in-Aid for Scientific Research [24107005] Funding Source: KAKEN

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A photocathode for CO2 reduction was successfully developed using a hybrid electrode comprising a Ru(II)-Re(I) supramolecular photocatalyst and a NiO electrode. Selective photoexcitation of the Ru photosensitizer unit of the photocatalyst at -1.2 V vs. Ag/AgNO3 selectively afforded CO with high faradaic efficiency.

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