4.7 Article

Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 84, 页码 15358-15361

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc07073b

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资金

  1. 973 Project [2012CB821704, 2014CB845602]
  2. NSFC [91122032, 91422302, 21301197]
  3. NSF of Guangdong [S2013020013002]
  4. Spanish Ministerio de Economia y Competitividad [CTQ2011-23862-C02-01]
  5. Generalitat de Catalunya

向作者/读者索取更多资源

The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(III) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation.

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