Novel trifunctional electrocatalyst of nickel foam supported Co2P/NiMoO4 heterostructures for overall water splitting and urea oxidation

The process of electrocatalytic water splitting for hydrogen generation is significantly limited by sluggish kinetics of the anodic oxygen evolution reaction (OER). The efficiency of H2 electrocatalytic generation can be improved by reducing the anode potential or substituting urea oxidation reaction (UOR) for oxygen evolution process. Here, we report a robust catalyst based on Co2P/NiMoO4 heterojunction arrays supported on nickel foam (NF) for water splitting and urea oxidation. In the hydrogen evolution reaction in alkaline media, the optimized catalyst Co2P/NiMoO4/NF displayed a lower overpotential (169 mV) at a large current density (150 mA cm-2) compared to 20 wt% Pt/C/NF (295 mV@150 mA cm-2). In the OER and UOR, the potentials were as low as 1.45 and 1.34 V. These values surpass (for OER), or compare favorably to (for UOR), the most advanced commercial catalyst RuO2/NF (at 10 mA cm-2). This outstanding performance was attributed to the addition of Co2P, which has a significant effect on the chemical environment and electron structure of NiMoO4, while increasing the number of active sites and promoting charge transfer across the Co2P/NiMoO4 interface. This work proposes a high-performance and cost-effective electrocatalyst for water splitting and urea oxidation.

Automated summary

In this study, a stable catalyst based on Co2P/NiMoO4 heterojunction arrays supported on nickel foam was reported for water splitting and urea oxidation. The catalyst exhibited lower overpotential and higher catalytic performance at a large current density compared to a commercial catalyst RuO2/NF. The addition of Co2P was found to significantly affect the chemical environment and electron structure of NiMoO4, increasing the number of active sites and promoting charge transfer across the Co2P/NiMoO4 interface.