期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 650, 期 -, 页码 1097-1104出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2023.07.040
关键词
Structured liquid; Arrested interface; Polyelectrolyte; Aliphatic surfactant; Fatty alcohol
Experiments revealed the formation of solid films at liquid interfaces through the interfacial association of anionic polyelectrolytes and surfactants. These films possess temperature sensitivity and offer an alternative to previously synthesized solid polyion/surfactant assemblies.
Hypothesis: Sculpting liquids into different shapes is usually based on the interfacial interactions of functionalized nanoparticles or polymers with specific ligands, leading to exciting material properties due to the combination of the mobility of liquid components with the solid-like characteristic of the arrested liquid/liquid interface. There is an intense interest in novel structured liquids produced from simple compounds with versatile application potentials. Complexes of oppositely charged commercial polyelectrolytes and traditional aliphatic surfactants are good candidates for this goal since they reveal rich structural features and could adsorb at various interfaces. However, they have not been applied yet for structuring liquids. Experiments: The interfacial interactions and film formation between aqueous sodium poly(styrene) sulfonate solutions (NaPSS) and hexadecylamine (HDA) solutions in various alkanols were investigated by surface tension measurements and ATR-IR spectroscopy. 3D printing experiments also assessed the robustness of the formed films.Findings: Arrested fatty alcohol/water interfaces were formed due to the interfacial association of NaPSS, HDA, and alkanol molecules, which also act as cosurfactants in the surface region. These solid films enable the synthesis of temperature-sensitive all-in-liquid constructs and offer alternatives to bulk polyion/mixed surfactant assemblies prepared earlier through numerous synthesis steps.
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