期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 645, 期 -, 页码 735-742出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2023.04.133
关键词
In-situ electrochemical reduction; Interface; CO2RR; Copper-based catalysts
Electrochemical carbon dioxide reduction reaction (CO2RR) is an effective method to capture and convert CO2 into valuable chemicals and fuels, reducing CO2 emissions. Copper-based catalysts have shown excellent performance in converting CO2 into multi-carbon compounds and hydrocarbons. However, their selectivity towards coupling products is poor.
Electrochemical carbon dioxide reduction reaction (CO2RR) is an effective approach to capture CO2 and convert it into value-added chemicals and fuels, thereby reducing excess CO2 emissions. Recent reports have shown that copper-based catalysts exhibit excellent performance in converting CO2 into multi-carbon compounds and hydrocarbons. However, the selectivity to the coupling products is poor. Therefore, tuning CO2-reduction selectivity toward C2+ products over Cu-based catalyst is one of the most important issues in CO2RR. Herein, we prepare a nanosheet catalyst with interfaces of Cu0/Cu+. The catalyst achieves Faraday efficiency (FE) of C2+ over 50% in a wide potential window between - 1.2 V to - 1.5 V versus reversible hydrogen electrode (vs. RHE). Moreover, the catalyst exhibits maximum FE of 44.5% and 58.9% towards C2H4 and C2+, with a partial current density of 10.5 mA cm-2 at - 1.4 V. Density functional theory (DFT) calculations show that the interface of Cu0/ Cu+ facilitates C-C coupling to form C2+ products, while inhibits CO2 conversion to C1 products.
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