4.7 Article

Synergistic assisted hydrogen production of tailings slurry and coal slurry: Process and mechanism investigation

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JOURNAL OF CLEANER PRODUCTION
卷 422, 期 -, 页码 -

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ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2023.138582

关键词

Coal-assisted water electrolysis; Hydrogen production; Lead-zinc tailings; Ferrous ions

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This study investigated the process and mechanism of synergistically assisted hydrogen production from tailings and coal slurry. It was found that the influence of lead-zinc tailings extract is primary while the electrocatalysis of Fe3+ has only a slight impact on current density increase.
This study investigated the process and mechanism of synergistically assisted hydrogen production from tailings and coal slurry. We have identified the optimal tailings as lead-zinc tailings through experimentation with different tailings mixed with pulverized coal. Furthermore, we have analyzed the electrochemical properties of Fe2+ and Fe3+ at different concentration gradients in a hydrochloric acid environment and our results have confirmed that the presence of Fe3+ in the simplified environment does not affect the electrochemical processes. to determine the respective roles and effects of the extract and residue of the lead-zinc tailings slurry with equal amounts of coal dust added to them, which has confirmed that it is the lead-zinc tailings extract that has the primary influence. In addition, the electrocatalysis of Fe3+ in the presence of both lead-zinc tailings and coal results in a small increase in current density, and the improvement in current density due to direct and indirect oxidation of coal particles is also extremely limited. Based on our analysis, we have concluded that the increase in current density brought about by the synergistic hydrogen production from lead-zinc tailings-supported coal is mainly due to the different oxidation processes of Fe2+.

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