期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 56, 页码 11240-11243出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc03995a
关键词
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资金
- Chinese National Natural Science Foundation [21173178, 21232005, 21375113]
- National Basic Research Program of China [2012CB821600]
- [2014Y0068]
A new and general method for the synthesis of beta-azidophosphonates has been achieved throughMn(OAc)(3)-mediated radical oxidative phosphonation-azidation of alkenes. The starting materials of P(O)-H compounds, alkenes, and azidotrimethylsilane are stable and cheap. This method can be easily adapted for large-scale preparation.
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