期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 76, 页码 14365-14368出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05239d
关键词
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资金
- Ministry of Education of China
- Shenzhen Government [CXZZ20140419131807788, JCYJ20140627145302109]
- Guangdong Government [S20120011226]
- National Science Foundation of China [21332005]
- MOST of China [2014AA020512]
Using an internally oxidizing directing group (DG) strategy, we report a Rh-III-catalyzed synthesis of isoquinolones via C-H activation/annulation of benzoylhydrazines and alkynes. Tunable double cascade cyclization of benzoylhydrazines with two equivalents of alkynes led to tetracyclic amides. These N-heterocycles demonstrated adjustable AIE properties.
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