期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 84, 页码 15394-15397出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05084g
关键词
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资金
- National Natural Science Foundation of China [21202049]
- Recruitment Program of Global Experts (1000 Talents Plan)
- Fujian Hundred Talents Program and Program of Innovative Research Team of Huaqiao University [Z14X0047]
A copper-catalyzed highly efficient protocol for the synthesis of bis-deuterated beta-borylated alpha, beta-styrene derivatives, which can be further transformed to practical isotopically labeled compounds, has been developed. Alkynyl carboxylic acids are employed as alkyne synthons yet demonstrate a sharp discrepancy in reactivity and selectivity compared to terminal alkynes. Meanwhile, this reaction offers a novel and efficient strategy for highly selective trifunctionalization of the carbon-carbon triple bond at ambient temperature.
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