期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 79, 页码 14728-14731出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc05183e
关键词
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资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Natural Science Foundation of China [21272165]
- Natural Science Foundation of China (NSFC) [21302015, 21302133]
Through merging Cu-based carbenes in a radical process, a novel crossover reaction has been successfully established, leading to the facile and efficient syntheses of various gamma-peroxy esters and 1,4-dicarbonyl compounds. Considering that both Cu-based carbene complexes and radicals are extremely reactive, and therefore exist only in extraordinarily low concentrations, the high selectivity of this coupling reaction is unusual.
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