4.7 Article

Li-Ca alloy-LiF hybrid layer formed in situ to realize high performance lithium metal batteries

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 960, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.170788

关键词

Lithium metal anode; Li-Ca alloy; Artificial SEI; Hybrid layer; Li plus transport

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The lithium metal anode is favored due to its high theoretical specific capacity. However, lithium metal batteries (LMBs) suffer from challenges such as uncontrolled growth of lithium dendrites and an unstable interface during electrodeposition and exfoliation. In this study, a simple chemical immersion method is used to construct a Li-Ca alloy protective layer and a LiF-rich interface, leading to improved performance of the lithium anode. The treated lithium shows stable cycling over 3000 hours and excellent cycle performance in the Li-LiFePO4 cell.
The lithium metal anode is a desirable choice owing to its high theoretical specific capacity. Despite their promising potential, lithium metal batteries (LMBs) face significant challenges in practical applications, such as uncontrolled growth of lithium dendrites and an unstable interface that occurs during repeated deposition and exfoliation of the lithium anode Therefore, this study employs a simple chemical immersion method, which can not only construct a Li-Ca alloy protective layer to improve lithium-ion transport but also provide a LiF-rich interface to further enhance the mechanical strength of the protective layer. The obtained Li-Ca alloy-LiF hybrid layer shows improved performance of the lithium anode. The results in-dicate that the Li-Li symmetric cell composed of the treated Li can undergo stable cycling over 3000 h under various cycling conditions and also exhibit excellent cycle performance in the Li-LiFePO4 cell. & COPY; 2023 Elsevier B.V. All rights reserved.

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