4.7 Article

The enhanced xylene gas sensing selectivity in p-type CuCo2O4 hierarchical architectures

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JOURNAL OF ALLOYS AND COMPOUNDS
卷 959, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.170569

关键词

Xylene; Selectivity; Catalytic oxidation; Gas sensor

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High selective detection of the target gas is crucial for gas sensors. This study investigates the dominant factor affecting sensing selectivity and presents CuCo2O4-based gas sensing materials. The CCO-400 sensor shows excellent selectivity towards xylene gas at a working temperature of 150 degrees C, along with stability, repeatability, and a low detection limit of 0.5 ppm. The enhanced selectivity is attributed to the catalytic promotion of the Co component towards xylene gas.
Realizing high selective detection toward the target gas is one of the most important evaluation indexes of the gas sensors. Revealing the dominant factor affecting sensing selectivity has always been the focus and keynote of gas sensing research fields and the hinge to optimize material selectivity. In this manuscript, a series of CuCo2O4 based gas sensing materials have been prepared by annealing CuCo2O4 precursors synthesized by a feasible hydrothermal reaction. The gas sensor based on CCO-40 0 (CuCo2O4 annealed at 400 degrees C) shows superior selectivity toward xylene gas at a working temperature of 150 degrees C. Meanwhile, the CCO-40 0 sensor also presents well stability, repeatability and a low detection limit of 0.5 ppm. The enhanced xylene gas sensing selectivity of the CCO-40 0 sensor is prominently attributed to the catalytic promotion of the Co component toward xylene gas, advancing the dissociation of the less reactive xylene. (c) 2023 Elsevier B.V. All rights reserved.

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