期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 948, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.169770
关键词
Transition metal oxides; Electrochemical properties; Asymmetric supercapacitors
By engineering novel transition metal oxide materials with micro/nanostructures, unusual electrochemical properties are achieved. In this study, MoV2O8/MoO3 microclusters (MVO/MO MCs) were synthesized through a simple hydrothermal process. The optimized MVO/MO MC electrode exhibited a superior specific capacity of 392.58 mAh g-1, as well as excellent capacity retention and coulombic efficiency. Pouch-like asymmetric supercapacitors (ASCs) fabricated with MVO/MO MCs and activated carbon materials showed high power and energy densities, as well as superior capacity retention and coulombic efficiency.
Engineering novel transition metal oxide materials with micro/nanostructures has endowed unusual electrochemical properties. Herein, we reported the MoV2O8/MoO3 microclusters (MVO/MO MCs) synthesized by a simple and facile hydrothermal process. Furthermore, the MVO/MO MC-based electroactive materials were studied at various annealing temperatures of 300, 400, and 500 & DEG;C. The prepared materials wrere characterized via different analysis methods for the investigation of phase, morphology, surface area, and oxidation states. The optimized MVO/MO MC electrode revealed a superior specific capacity of 392.58 mAh g-1 at 1 A g-1 (2844 F g-1) in a 1 M KOH electrolyte solution. The MVO/MO MC electrode also exhibited excellent capacity retention of 101% with a corresponding coulombic efficiency of 99%. Accordingly, the fabricated pouch-like asymmetric supercapacitor (ASC) with the MVO/MO MCs and activated carbon materials delivered maximum power and energy densities of 2306.95 W Kg-1 and 37.06 Wh kg-1, respectively. Additionally, the ASC showed superior capacity retention of 128% with 97% of coulombic efficiency. Also, the ASC devices were employed to test the practical application by powering electronic gadgets. & COPY; 2023 Elsevier B.V. All rights reserved.
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