期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 952, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.169980
关键词
Sodium -selenium batteries; Carbon host materials; Shuttle effect; Polyselenide; C; Se composite cathode
This review paper provides a comprehensive overview of C/Se composite as the cathode material for Na-Se batteries. It highlights different carbon hosts based on hierarchical porous structure and adsorption effect, offering valuable insights into the rational design and operating principle. Since research on Na-Se batteries is still in its early stage, this work is expected to inspire more visionary ideas.
In sodium chalcogen batteries, selenium has attracted greater attention in Na-Se batteries due to its attractive theoretical capacity and conductivity which is 20 orders of magnitude higher than that of sulfur. However, the capacity of the battery suffers from the shuttle effect, which limits its further enhancement. Therefore, the design of C/Se composite cathode that can alleviate volume expansion, accelerate electron transport, and inhibit polyselenide dissolution by using carbon matrix as selenium host has become a hot topic of extensive research nowadays. This paper makes a comprehensive review of C/Se composite as the cathode of Na-Se battery, distinguishing and highlighting different carbon matrices from the perspectives of hierarchical porous structure and adsorption effect, providing valuable insights into the rational design of carbon hosts and the analysis of operating principle. The research on Na-Se batteries is still in a relatively primary stage, and this work is expected to stimulate more visionary ideas. (c) 2023 Elsevier B.V. All rights reserved.
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