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Article
Agricultural Engineering
Bernd G. K. Steiger et al.
Summary: In this study, torrefied wheat straw and oat hulls were combined with kaolinite and chitosan to obtain pelletized adsorbent materials. The composites were compared to spent coffee grounds as a reference biomass system. IR and C-13 NMR spectroscopy were used for structural characterization, and a cationic dye probe was employed to evaluate the adsorption properties. The results showed that crosslinking notably reduced the adsorption capacity for torrefied biomass composites, while greater uptake occurred for the spent coffee grounds composites. A cost-benefit analysis indicated that the torrefied wheat straw composites are competitive adsorbents per dollar material cost compared to the spent coffee grounds composites. Pelletized adsorbent technology with torrefied biomass offers lower chemical input costs and sustainability.
INDUSTRIAL CROPS AND PRODUCTS
(2023)
Article
Green & Sustainable Science & Technology
Ali H. Jawad et al.
Summary: In this study, a novel hybrid multifunctional biocomposite of chitosan grafted-benzaldehyde/montmorillonite/algae (CHS-BZ/MT/AL) was designed and applied for highly efficient removal of brilliant green (BG) and reac-tive blue 19 (RB19) dyes from water. The effects of CHS-BZ/MT/AL dose, pH solution, and contact time on the removal rate of BG and RB19 dyes were investigated using response surface methodology. The experimental results showed that CHS-BZ/MT/AL had a maximum adsorption capacity of 899.5 mg/g for BG and 213.6 mg/g for RB19.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Engineering, Environmental
Nurul Izzati Normi et al.
Summary: The present study focused on the grafting of biopolymer chitosan with an aromatic aldehyde via hydrothermal technique for the adsorption of an azo dye from water. The CHS-SA material obtained demonstrated a high adsorption capacity for the dye, and various interaction mechanisms were found to be involved in the adsorption process.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Environmental Sciences
M. Hussain et al.
Summary: This research optimized the parametric conditions for treating heavy metals contaminated wastewater using composite beads synthesized from Acacia nilotica biochar and chitosan. The results showed that the synthesized material had good stability, amorphous structure, porous surface, and functional groups that played a significant role in heavy metal adsorption. The optimized conditions achieved excellent removal percentages for Cd, Cr, Ni, and Pb, indicating that the synthesized chitosan combined biochar composite is a promising material for wastewater treatment.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Biotechnology & Applied Microbiology
Gulay Bayramoglu et al.
Summary: Tramates trogii biomass was immobilized in carboxymethyl cellulose-lignin composite beads cross-linked with Fe(III) ions for the adsorption and degradation of bisphenol A (BPA). The maximum adsorption capacity of the immobilized biomass was higher than that of the free fungal biomass. The degradation rates of BPA were high for both the free biomass and the immobilized biomass.
Article
Chemistry, Applied
Shadpour Mallakpour et al.
Summary: The fabrication of environmentally friendly nanocomposite beads containing chitosan, tannic acid, layered double hydroxides, and mixed metal oxides was successful. These beads showed excellent adsorption capacity for three reactive dyes and could be regenerated and reused multiple times.
CARBOHYDRATE POLYMERS
(2023)
Article
Engineering, Environmental
Zahirah Mohd Zain et al.
Summary: This study developed a pH-sensitive chitosan/sepiolite clay/algae biocomposite for efficient removal of cationic and anionic dyes by adjusting the solution pH. The optimal conditions for dye removal were determined using a Box-Behnken design and the adsorption mechanism was investigated. The biocomposite exhibited high adsorption capacity and the adsorption process was confirmed to be endothermic and spontaneous. Various interactions, such as electrostatic, H-bonding, and n-pi interactions, contributed to the adsorption mechanism.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2023)
Article
Chemistry, Multidisciplinary
Imane Akkari et al.
Summary: Hydrothermal Carbonization is an easy, inexpensive, and eco-friendly method to convert waste into sustainable materials. This study used this method to make hydrochar from pomegranate peels and found that it performed well in removing a cationic dye from water. The prepared hydrochar showed good reusability and could be an effective adsorbent for treating colored wastewater.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2023)
Article
Engineering, Environmental
Daikun Li et al.
Summary: In this study, an aminated waste paper (WP-NH2) membrane was successfully prepared by oxidation, grafting, and crosslinking of polyethyleneimine (PEI) on various types of waste paper. WP-NH2 exhibited high adsorption capacity for anionic dyes and antibiotics and remained stable after multiple regenerations. Mechanistic studies revealed the adsorption mechanisms for different contaminants. The WP-NH2 membrane efficiently filtered out dyes and antibiotics from water, showing high selectivity and potential application in industrial wastewater remediation.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Chemistry, Analytical
Mostafa Solgi et al.
Summary: An agro-waste composite in pelletized form was prepared and characterized using IR and C-13 solids NMR spectroscopy. The study investigated the adsorption properties of the composite for sulfate under equilibrium and dynamic conditions. The Langmuir and Freundlich models were employed to estimate the adsorption capacity, while the Thomas and Yoon-Nelson models were used to analyze the breakthrough curves. The optimal conditions for sulfate separation were determined, and the study contributes to the development of sustainable water treatment systems.
Article
Environmental Sciences
Negar Beigi et al.
Summary: In this study, a simple one-pot solvothermal approach has been used to create magnetic porous carbon nanocomposites obtained from a nickel-based metal-organic framework (Ni-MOF) for the adsorption of methyl orange (MO) dye. The derived carbons, known as CDM-700, CDM-800, and CDM-900, exhibited exceptional porosity and magnetic properties when pyrolyzed at different temperatures under a nitrogen atmosphere. Various analysis methods were employed to characterize the prepared powders. The maximum adsorption capacities of Ni-MOF, CDM-700, CDM-800, and CDM-900 for MO dye were found to be 307.38, 5976.35, 4992.39, and 2636.54 mg/g, respectively. The synthesized nanocomposite showed promising potential as a superadsorbent for dye removal from contaminated water.
ENVIRONMENTAL RESEARCH
(2023)
Article
Chemistry, Physical
Yunxin Shi et al.
Summary: A series of donut-like nanostructured heterojunction materials were synthesized to enhance the photocatalytic efficiency for environmental pollutants. The Fe-doped-BiOCl@Fe-MOF heterojunction showed optimal photocatalytic efficiency in the degradation of RhB (99.0%, 90 min) and TC (90.4%, 90 min) solution, surpassing previously reported materials. The mechanism involved the synergistic effect of Fe-MOF and Fe-doped BiOCl, with h+ and & BULL;O2 identified as the primary active species.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Article
Materials Science, Multidisciplinary
Ankurita Nath et al.
Summary: In this study, eggshell powder (ESP) was used as a selective heterogeneous catalyst for the oxidative degradation of crystal violet (CV) dye in aqueous media. ESP acted as a carbonate (CO32) source, facilitating the formation of carbonate anion radicals (CO3 (center dot-)) in the presence of H2O2. The combination of these radicals and center dot OH radicals led to the selective degradation of CV dye. The use of ESP as a catalyst offers a promising route for CV degradation and the utilization of eggshell waste.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Amr M. Emara et al.
Summary: To remove radioactive cesium ions from wastewater, researchers synthesized graft copolymer of chitosan-g-poly(acrylic acid/N-vinylcaprolactam) [CTS-P(AA/VC)]. The copolymer's shape, thermal stability, and structure were characterized using SEM, TGA, and FT-IR. Batch sorption experiments were conducted to evaluate the effects of various parameters on the adsorption process. Kinetics data were analyzed using different models, and the Langmuir and Freundlich equations were used for isotherm modeling. The copolymer showed promising potential in treating cesium-134 ions-containing liquids.
RADIATION PHYSICS AND CHEMISTRY
(2023)
Article
Chemistry, Physical
Gulay Bayramoglu et al.
Summary: In this study, various green biosorbents based on Oscillatoria princeps biomass were developed for dye removal from wastewaters. The modified algal biomasses showed enhanced biosorption capacities for Reactive Red 120 dye compared to the native algal biomass, and the biosorption process was governed by hydrogen bonding, ion exchange, electrostatic, and pi-pi interactions. The biosorbents also displayed good regeneration capabilities, making them promising for practical applications in wastewater treatment.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Engineering, Environmental
Ali H. Jawad et al.
Summary: A new biocomposite adsorbent with magneto-responsiveness was prepared and applied for the removal of a synthetic textile dye. The adsorption parameters were optimized using statistical analysis, and the equilibrium dye uptake and kinetic behavior were studied. The maximum adsorption capacity of the adsorbent was determined, and its separation ability was highlighted. The magnetic adsorbent can be easily separated from the treated solution, making it suitable for industrial applications in continuous flow systems.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Review
Environmental Sciences
M. H. Mohamed Noor et al.
Summary: The study explores the roles and benefits of integrating magnetic nanoparticles in coagulation/flocculation for water treatment, including reducing the use of conventional coagulant/flocculant, shortening process duration, and enabling recovery of used materials through an external magnetic field. Further research on physico-chemical characteristics of magnetic flocs and toxicological/economic implications is recommended for a better understanding of the process.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2022)
Article
Environmental Sciences
Palak Saket et al.
Summary: This review analyzes the role of biological (microalgae) and synthetic (bio-polymeric adsorbents) elements in the treatment of water pollutants, highlighting their strengths and limitations. The integration of these two technologies can enhance removal efficiencies in an environmentally safe and cost-effective manner.
INTERNATIONAL JOURNAL OF PHYTOREMEDIATION
(2022)
Article
Green & Sustainable Science & Technology
Jianlong Wang et al.
Summary: Chitosan is a natural biopolymer with a modifiable structure and abundant functional groups, making it suitable for various applications. This review analyzes and summarizes recent advances in chitosan-based materials, particularly focusing on the modification of chitosan by physical, chemical, and biological methods. The review provides plentiful information on the preparation, characterization, and application of chitosan-based materials, including various preparation and modification methods for improving chitosan performances.
JOURNAL OF CLEANER PRODUCTION
(2022)
Review
Environmental Sciences
Gomathi Ramalingam et al.
Summary: Water is essential for all living things, but industrialization has led to water contamination, affecting ecosystems. The lack of treatment in reusing wastewater is the root issue. Therefore, water treatment is crucial for preserving the ecosystem and human health. In recent years, graphene-based photocatalysts have gained attention for their exceptional properties in wastewater treatment.
Article
Engineering, Environmental
Joanna Kurczewska
Summary: In this study, chitosan beads with incorporated montmorillonite were prepared and characterized. The results showed that the chitosan beads with montmorillonite had better adsorption capacity for methyl green removal. Several parameters were investigated to optimize the process.
JOURNAL OF WATER PROCESS ENGINEERING
(2022)
Article
Engineering, Environmental
Rania M. Eltabey et al.
Summary: In this study, poly(maleic acid)-grafted cross-linked chitosan/montmorillonite composite nanospheres (PMAL-CTS/MMT) were synthesized for efficient adsorption of organic dyes. The high adsorption capacity of PMAL-CTS/MMT towards both anionic and cationic dyes can be attributed to the presence of abundant functional groups. The surface charges of PMAL-CTS/MMT can be modulated by adjusting the solution pH, resulting in enhanced affinity towards different types of dyes. The proposed adsorption mechanism involves electrostatic interaction, pi - pi interactions, and hydrogen bonding. Additionally, PMAL-CTS/MMT was successfully utilized for the separation of dyes from real-life aquatic environments.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Multidisciplinary Sciences
Asiyeh Kheradmand et al.
Summary: In this study, a treated lignocellulosic biomass waste supported composite was synthesized and found to be effective for dye removal. The composite showed high removal efficiency under certain conditions.
SCIENTIFIC REPORTS
(2022)
Article
Biotechnology & Applied Microbiology
Ahmed Saud Abdulhameed et al.
Summary: In this study, microalgae (MAG) was used as an environmentally friendly and efficient adsorbent for the removal of crystal violet (CV) and methylene blue (MB) dyes from aqueous solutions. The adsorption process was optimized using a Box-Behnken design (BBD), and the kinetics and isotherm analyses revealed that the adsorption followed the pseudo-second-order and Langmuir models. MAG exhibited a maximum adsorption capacity of 243.0 mg/g for CV and 297.1 mg/g for MB. The thermodynamic parameters indicated that the adsorption of CV and MB dyes onto MAG was spontaneous and endothermic. The adsorption mechanism involved electrostatic forces, n-?? stacking, and H-bonding. Overall, MAG shows promise as an effective adsorbent for removing dyestuffs from industrial effluent.
ALGAL RESEARCH-BIOMASS BIOFUELS AND BIOPRODUCTS
(2022)
Article
Biotechnology & Applied Microbiology
Belete Geremew et al.
Summary: In this study, Hagenia abyssinica leaf powder (HALP) adsorbent was used to successfully remove methyl violet dye from aqueous solution. The optimum adsorption conditions were determined as 0.2 g adsorbent dose, 100 mg/L dye solution, 50 min contact time, and a solution pH of 6. The adsorption process followed the Langmuir model with a high adsorption capacity. The thermodynamic data indicated that the adsorption process is endothermic, spontaneous, and exhibits randomness at the HALP/solution interface.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2022)
Article
Chemistry, Multidisciplinary
Mai El-Kammah et al.
Summary: This study proposed the development of a nanoscale adsorbent material using waste from Moringa oleifera seeds for the removal of Indigo Carmine from textile effluents. The adsorption process was found to fit the Langmuir isotherm in the equilibrium of adsorption and the power function in the kinetic behavior. The maximum adsorption capacity of the absorbent nanoparticles was significantly higher than that of the bulk Moringa oleifera seeds. The dominant mechanisms of Indigo Carmine adsorption on the nanoparticles were identified as hydrogen bonding, electrostatic interlinkage, and pi-pi interactions. The Moringa oleifera seed nanoparticles showed promise as a green and low-cost adsorbent for textile wastewaters.
SUSTAINABLE CHEMISTRY AND PHARMACY
(2022)
Article
Materials Science, Multidisciplinary
Aiman Suhaimi et al.
Summary: In this study, carrot juice pulp and pomegranate peel were used to produce high surface area activated carbon through microwave radiation and ZnCl2 activation. The activated carbon showed great adsorption capacity for crystal violet dye, making it a potential material for wastewater treatment.
DIAMOND AND RELATED MATERIALS
(2022)
Article
Engineering, Chemical
Esra Altintig et al.
Summary: In this study, chitosan-coated clinoptilolite zeolite was investigated as an adsorbent for the removal of methyl violet from aqueous solutions. The adsorbent was characterized and its effectiveness was examined under various parameters. The experimental data showed that the adsorption isotherms followed the Langmuir equilibrium isotherm model equation, and the maximum adsorption capacity was found to be 111.11 mg g(-1) at 318 K. The adsorption of methyl violet was found to conform to the pseudo-second-order kinetic model. A neural network model was developed to predict dye removal, and it was concluded that it could be used effectively. Overall, the developed chitosan coating on clinoptilolite zeolite composite proved to be a natural, cost-efficient, and eco-friendly adsorbent for the removal of methyl violet from aqueous solutions.
DESALINATION AND WATER TREATMENT
(2022)
Article
Water Resources
Mohamed H. Mohamed et al.
Summary: This study aimed to prepare a low-cost sustainable adsorbent material with tailored Pb(II) adsorption properties. The optimal composite adsorbent, consisting of chitosan, kaolinite, and oat hulls, demonstrated high adsorption capacity for lead removal. The biocomposite adsorbent showed favorable adsorption properties and can be used as a disposable filter media for the removal of lead and other multivalent heavy metal cations.
FRONTIERS IN WATER
(2022)
Review
Engineering, Environmental
Ismaila Olalekan Saheed et al.
Summary: Modification of chitosan through methods such as grafting and cross-linking is a promising approach for removing organic and inorganic pollutants from aqueous medium. The performance of modified chitosan for adsorption of pollutants depends largely on the modification method adopted, materials used, and adsorption experimental conditions. Cross-linking is commonly used for improving the stability of chitosan, although it may decrease adsorption capacity, but recent works have shown enhancement through grafting or incorporation of solid adsorbents before cross-linking.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Article
Biotechnology & Applied Microbiology
Camilo Zamora-Ledezma et al.
Summary: The article discusses the causes of water pollution, the potential risks of heavy metal contamination to the environment and human health, and the technologies and materials available for purifying water sources. It highlights the human activities as the main source of heavy metals, the health hazards posed by them, and various detection and removal methods.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2021)
Article
Chemistry, Physical
Truong Thi Phuong Nguyet Xuan Trinh et al.
Summary: Three-dimensional graphene aerogel materials were fabricated using ethylenediamine and graphene oxide sheets, and showed high adsorption capacities for methylene blue and methyl orange. Optimal adsorption conditions and mechanisms were identified through experiments.
SURFACES AND INTERFACES
(2021)
Article
Environmental Sciences
B. Senthil Rathi et al.
Summary: Emerging pollutants in the marine ecosystem are becoming a growing concern, as traditional wastewater treatment plants are not able to completely remove these contaminants, leading to the need for cost-effective additional water treatment methods. Adsorption is a successful method for contaminant removal globally, due to its low cost, high performance, and simple design.
ENVIRONMENTAL POLLUTION
(2021)
Article
Biochemistry & Molecular Biology
Zeynep Mine Senol
Summary: This paper describes a green and cost-effective approach to investigate Ch-Sep composite as an adsorbent for removal of UO22+ ions in aqueous solution. The study evaluates the adsorption properties, isotherm models, kinetics, and thermodynamics parameters of UO22+ ions removal using Ch-Sep composite beads, showing its potential effectiveness for the removal of UO22+ ions.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Biochemistry & Molecular Biology
Seyed Davoud Ashrafi et al.
Summary: This study synthesized CA/MWCNTs and studied its efficiency in adsorbing 4-NP, finding that MWCNTs can increase the adsorption capacity and that the synthesized adsorbent can be reused multiple times without significant reduction in efficiency.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Biochemistry & Molecular Biology
Rais Ahmad et al.
Summary: This paper synthesized an eco-friendly and low-cost chitosan modified hybrid Azadirachta indica leaves powder-Kaolinite clay nanocomposite and investigated its potential as an adsorbent for removing hazardous dyes from aqueous solution. The results showed that the nanocomposite had good adsorption capacity for Congo red and Methylene blue dyes, with the ability to be successfully regenerated multiple times. The study also found that the adsorption process followed pseudo second order kinetics and had thermodynamic parameters indicating spontaneous and endothermic nature.
PROCESS BIOCHEMISTRY
(2021)
Review
Biochemistry & Molecular Biology
Prasanna S. Bakshi et al.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2020)
Article
Polymer Science
Hongduo Tang et al.
POLYMER SCIENCE SERIES A
(2020)
Article
Microbiology
Felipe Robledo-Padilla et al.
Review
Environmental Sciences
Angelika Tkaczyk et al.
SCIENCE OF THE TOTAL ENVIRONMENT
(2020)
Review
Chemistry, Physical
Tahir Rasheed et al.
JOURNAL OF MOLECULAR LIQUIDS
(2020)
Article
Chemistry, Multidisciplinary
Imran Ali et al.
Article
Environmental Sciences
Onur Can Turker et al.
INTERNATIONAL JOURNAL OF PHYTOREMEDIATION
(2018)
Article
Biochemistry & Molecular Biology
Ali Zeraatkar Moghaddam et al.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2018)
Article
Engineering, Environmental
Gulay Bayramoglu et al.
WATER SCIENCE AND TECHNOLOGY
(2017)
Article
Engineering, Environmental
Prangya Ranjan Rout et al.
JOURNAL OF WATER PROCESS ENGINEERING
(2017)
Article
Engineering, Chemical
Hadi Shayesteh et al.
DESALINATION AND WATER TREATMENT
(2016)
Article
Chemistry, Applied
You Wei Chen et al.
CARBOHYDRATE POLYMERS
(2016)
Article
Chemistry, Physical
Saeid Moradi et al.
JOURNAL OF MOLECULAR LIQUIDS
(2016)
Article
Engineering, Environmental
L. R. Bonetto et al.
JOURNAL OF WATER PROCESS ENGINEERING
(2015)