期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 220, 期 -, 页码 183-187出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.micromeso.2015.09.005
关键词
Ordered mesoporous silica; SBA-15; Water vapor sorption; Structure property relation; Tailored adsorbent
类别
资金
- Excellence Initiative of the German federal government [OPBF053]
- Excellence Initiative of the German state government [OPBF053]
In order to establish a structure-property correlation in water vapor sorption, various sets of the ordered mesoporous silica SBA-15 with systematically varying properties were synthesized and characterized. General trends concerning the surface polarity, aging temperature during synthesis and micropore volume were observed. Calcining the materials with increasing temperatures of 300-800 degrees C decreases the performance in water vapor sorption which correlates mainly with the amount and type of silanol groups on the silica surface. Furthermore, the aging temperature during synthesis influences the water vapor sorption capacity of SBA-15 at low relative pressure. The best results in terms of an increased uptake of water over a broad range of relative pressure can be obtained for materials with high micropore volume and high surface polarity. They can be tailor-made by using a routine to remove the template, i.e., a combination of extraction with ethanol and subsequent calcination at 300 degrees C. (C) 2015 Elsevier Inc. All rights reserved.
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