期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 17, 页码 3616-3619出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc10182k
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资金
- CEFIPRA/IFCPAR (Indo-French Center for the Promotion of Advanced Research)
Supramolecular organization of a metal complex may significantly contribute to the magnetization dynamics of mononuclear SMMs. This is illustrated for a heptacoordinated Fe(II) complex with rather moderate Ising-type anisotropy for which a slow magnetization relaxation with significant energy barrier was reached when this complex was properly organized in the crystal lattice. Incidentally, it is the first example of single-ion magnet behaviour of Fe(II) in a pentagonal bipyramid surrounding.
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