期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 31, 页码 6742-6745出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01562f
关键词
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资金
- NSF [CHE-1334703]
- DARPA [N66001-14-2-4058]
- MIT Lincoln Laboratories Advanced Concepts Committee [PO7000282490]
- 3M (Non-tenured Faculty Award)
Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions. We also demonstrate the on/off photo-switchability of this reaction under flow conditions.
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