期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 34, 页码 7352-7355出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00609k
关键词
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Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)-porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.
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