期刊
MICROCHIMICA ACTA
卷 183, 期 12, 页码 3221-3228出版社
SPRINGER WIEN
DOI: 10.1007/s00604-016-1974-5
关键词
Magnetite nanoparticles; Cyclic voltammetry; Amperometry; Double potential step chronoamperometry; Kinetics
资金
- National Basic Research Program of China [2013CB932902]
- Natural Science Foundation of Jiangsu [BK20141338, BK20161479]
- National Natural Science Foundation of China [51679076, 51301061]
- Priority Academic Program Development of Jiangsu Higher Education Institutions [1107047002]
We report on an electrochemical sensor for L-cysteine that consists of a glassy carbon electrode modified with a two-dimensional ternary nanocomposite prepared from platinum, magnetite, and reduced graphene oxide (referred to as Pt-Fe3O4/rGO). It was prepared by a solvothermal method and characterized by X-ray powder diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Electrochemical detection processes were investigated by cyclic voltammetry, amperometry, double potential step chronoamperometry and differential pulse voltammetry. The diffusion coefficient (7.41 x 10(-7) cm(2) s(-1)) and reaction rate constant (9.96 x 10(7) cm(3) mol(-1) s(-1)) were calculated via the Cottrell equation. The sensor, best operated in 0.1 M NaOH solution at a working voltage of 0.65 V vs. SCE, has a 10 mu M detection limit and an analytical range that extends from 0.10 to 1.0 mM. The method is acceptably selective, stable, repeatable and reproducible due to the synergistic effect of the various components applied. The detection limit is 1.0 x 10(-5) M.
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