期刊
MICROCHIMICA ACTA
卷 183, 期 3, 页码 1261-1268出版社
SPRINGER WIEN
DOI: 10.1007/s00604-016-1761-3
关键词
Magnetic solid phase extraction; Bamboo charcoal; PCBs; Water sample; GC-ECD
资金
- Program of National Natural Science of China [31170110]
- Research Encouragement Foundation of Excellent Midlife-Youth Scientists of Shandong Province [BS2015HZ014]
Magnetic matrix solid phase dispersion (MMSPD) assisted dispersive liquid liquid microextraction (DLLME) was applied to extract ultra traces of polychlorinated biphenyls (PCBs) from water samples prior to gas chromatography with electron capture detection. PCBs in water were adsorbed by micro particles of magnetic bamboo charcoal and then transferred into the elution solvent. PCBs in the elution solvent of the MMSPD were further concentrated into trace volume extraction solvent of the DLLME procedure. Under optimized conditions, good linearity in the range of 0.2-100 ng L-1 was obtained with regression coefficients (r) higher than 0.9987. Based on a signal-noise ratio of 3, the limits of detection (LODs) range from 0.05-0.1 ng L-1. These LODs are much lower than those of MMSPD or DLLME alone. Relative standard deviations are between 4.9-8.2 %. The method was successfully applied to the determination of PCBs in lake and river water. Relative recoveries were 85.5-117.4 % for the spiked environmental water samples.
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