期刊
INORGANIC CHEMISTRY
卷 62, 期 28, 页码 11080-11094出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.3c01136
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Binuclear half-lantern platinum(II) complexes [Pt(pbt)(mu-S boolean AND N)] 2 (pbtH = 2-phenylbenzothiazole, S boolean AND N = benzo[d]-thiazole-2-thiolate Pt1, 6-fluorobenzo[d]thiazole-2-thiolate Pt2, 6-chlorobenzo[d]thiazole-2-thiolate Pt3, 6-bromobenzo[d]thiazole-2-thiolate Pt4, and 6-iodobenzo[d]thiazole-2-thiolate Pt5) were synthesized with high yield by reacting [Pt(pbt)(NCMe)(2)]NO3 complex with appropriate benzo[d]thiazole-2-thiole in the presence of tBuOK. Complexes Pt1-5 exhibit intense red photoluminescence with high quantum yields. The substitution of H-to-F and H-to-Cl leads to significantly higher electroluminescence brightness, which is attributed to the intermolecular hydrogen bonding in the F-containing complex Pt2 and Cl-containing complex Pt3.
The binuclear half-lantern platinum(II) complexes [Pt(pbt)(mu-S boolean AND N)] 2 (pbtH = 2-phenylbenzothiazole, S boolean AND N = benzo[d]-thiazole-2-thiolate Pt1, 6-fluorobenzo[d]thiazole-2-thiolate Pt2, 6-chlorobenzo[d]thiazole-2-thiolate Pt3, 6-bromobenzo[d]thiazole-2-thiolate Pt4, and 6-iodobenzo[d]thiazole-2-thiolate Pt5) were synthesized by the treatment of the in situ formed [Pt(pbt)(NCMe)(2)]NO3 complex and appropriate benzo[d]thiazole-2-thiole in the presence of tBuOK; yield: 51-84%. Complexes Pt1-5 exhibit intense red photoluminescence originated from (MMLCT)-M-3 state reaching 22% room temperature quantum yields in a CH2Cl2 solution. All complexes display excited-state decay kinetics both in solution and in the solid state; the kinetics was adequately modeled by single exponentials. The complexes display more than 10-fold higher electroluminescence brightness for the F-containing Pt2 (900 cd/m(2)) and 2-fold higher electroluminescence brightness for the Cl-containing Pt3 (143 cd/m(2)) compared to the H-substituted complex Pt1 (77 cd/m(2)). It is argued that this impressive device luminance growth, occurred on formal replacement of H-to-F, is associated with the intermolecular strong hydrogen bonding H center dot center dot center dot F relevant to the H-bond found in the structure of Pt2.
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