期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 1, 页码 210-212出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07606k
关键词
-
资金
- National Natural Science Foundation of China [21172079, 21322606, 21436005]
- Guangdong Natural Science Foundation [10351064101000000]
A novel ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones is described. The process proceeded smoothly under metal-free conditions with high stereoselectivity and good functional group tolerance. The reaction mechanism was revealed to proceed through a domino reaction of oxidation and elimination after the radical addition to alkenes.
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