期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 33, 页码 7222-7225出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01189b
关键词
-
资金
- National Natural Science Foundation of China [21172106, 21174061, 21474048, 21372114]
A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate.
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