4.7 Article

C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-beta-glycoside formation

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 25, 页码 5394-5397

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08465a

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  1. Ministry of Science and Technology Department of Taiwan [MOST 102-2627-M-009-003]
  2. Center of Interdisciplinary Science (CIS) of NCTU

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We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-beta-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins.

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