4.7 Article

Click post-functionalization of a metal-organic framework for engineering active single-site heterogeneous Ru(III) catalysts

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 48, 页码 9884-9887

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02741a

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资金

  1. NSF of China [21322606, 21436005]
  2. Doctoral Fund of Ministry of Education of China [20120172110012]
  3. Fundamental Research Funds for the Central Universities
  4. Guangdong NSF [S2011020002397, 2013B090500027, 10351064101000000]

向作者/读者索取更多资源

We present a general strategy for incorporating pi-conjugated NNN-chelators (e.g., terpyridyl moiety) into a porous metal-organic framework (MOF) MIL-101(Cr) by using the click post-functionalization. The functionalized MOF could be used as a platform for metalation to yield highly active and stable single-site heterogeneous metal (e.g., Ru(III)) catalysts.

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