期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 19, 页码 4021-4023出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00315f
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资金
- RScF [14-13-00645]
- Russian Science Foundation [14-13-00645] Funding Source: Russian Science Foundation
Reaction of [Nb6O19](8-) with [Pt(OH)(4)(H2O)(2)] upon heating yielded first characterized platinum polyniobates. A dimeric complex [Nb6O19{Pt(OH)(2)}](2)(12-) (1) is produced in a 1 : 1 molar ratio. Increasing the Pt/Nb-6 molar ratio to 1 : 2 yields a mixture of 1 and a sandwich-type complex [Pt(Nb6O19)(2)](12-) (2).
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