期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 25, 页码 5359-5362出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08267b
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The syntheses of unsymmetrical N-heterocyclic carbenes (NHCs) that contain a single N-bound icosahedral carborane anion substituent are reported. Both anionic C-2 and doubly deprotonated dianionic C-2/C-5 NHC lithium complexes are isolated. The latter species is formed selectively, which reveals a surprising directing effect conveyed by icosahedral carborane anion substituents.
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