4.7 Article

Piezochromic luminescence behaviors of two new benzothiazole-enamido boron difluoride complexes: intra- and inter-molecular effects induced by hydrostatic compression

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 35, 页码 7497-7500

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc01902h

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资金

  1. Natural Science Foundation of China [21301085]
  2. Natural Science Foundation of Shandong Province [ZR2011BQ010]

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Two new propeller-shaped benzothiazole-enamide boron difluoride complexes exhibiting piezochromic luminescence upon mechanical grinding or hydrostatic compression were prepared. The two analogues displayed the red shift in luminescence under high pressure, while compound 2 with ICT effects showed a more sensitive piezochromic response at low pressure (<1.5 GPa). The different piezochromic luminescence behaviors of these compounds were investigated.

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