期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 75, 页码 14199-14202出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc02993g
关键词
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资金
- FAPESP (Research Supporting Foundation of the State of Sao Paulo) [2013/25504-1, 2013/17271-7]
- CNPq [301079/2012-9]
The conversion of biomass-derived levulinic acid (LA) into gamma-valerolactone (GVL) using formic acid (FA) and Fe-3(CO)(12) as the catalyst precursor was achieved in 92% yield. To mimic a biorefinery setting, crude liquor (containing 20% LA) from the acid hydrolysis of sugarcane biomass in a pilot plant facility was directly converted into GVL in good yield (50%), without the need for isolating LA.
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