Roles of metal oxide overlayers on hydrotalcite-structured Ni-MgAlOx for dry reforming of CH4 with CO2

Article Chemistry, Applied

Enhanced thermal stability of Ni nanoparticles in ordered mesoporous supports for dry reforming of methane with CO2

Kyung Soo Park et al.

Summary: A simple strategy was proposed to stably preserve smaller Ni nanoparticles by using ordered mesoporous supports, which effectively prevented thermal aggregations and coke depositions.

CATALYSIS TODAY (2022)

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Article Energy & Fuels

Key properties of Ni/CeAlO3-Al2O3/SiC-foam catalysts for biogas reforming: Enhanced stability and CO2 activation

Zhige Zhang et al.

Summary: The Ni/CeAlO3-Al2O3/SCF catalyst, with uniform distribution of Ni nanoparticles and activation of CO2 by CeAlO3, shows excellent catalytic stability in biogas reforming, inhibiting sintering and eliminating carbon deposition.

FUEL (2022)

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Article Energy & Fuels

Highly stable and coke-resistant Zn-modified Ni-Mg-Al hydrotalcite derived catalyst for dry reforming of methane: Synergistic effect of Ni and Zn

Anjaneyulu Chatla et al.

Summary: This study investigates the improvement of activity and carbon deposition-resistance of hydrotalcite-derived NiMgAl catalyst for dry reforming of methane by modifying it with different loadings of zinc. Addition of zinc enhances the metal-support interaction, stabilizes smaller Ni particles, and reduces carbon nanotube growth, leading to better catalytic performance and stability. The results suggest that the increased catalyst basicity and Ni-Zn alloy formation contribute to the enhanced resistance to deactivation by coking.

FUEL (2022)

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Article Chemistry, Applied

Confined Ni-In intermetallic alloy nanocatalyst with excellent coking resistance for methane dry reforming

Wenming Liu et al.

Summary: Carbon dioxide and methane are major greenhouse gases contributing to global warming, but dry reforming of methane (DRM) can convert them into useful products. However, the coking formation on nickel-based catalysts is a challenge for industrialization. Confined indium-nickel intermetallic alloy nanocatalysts show superior resistance to coking in DRM, with the In0.5Ni@SiO2 catalyst demonstrating the best balance of carbon deposition resistance and reactivity. This study provides guidance on designing high-performance catalysts for methane dry reforming to utilize greenhouse gases efficiently.

JOURNAL OF ENERGY CHEMISTRY (2022)

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Article Chemistry, Physical

Cooperatively enhanced coking resistance via boron nitride coating over Ni-based catalysts for dry reforming of methane

Jiang Deng et al.

Summary: The study proposes a boron nitride coating strategy on reducible oxides supported Ni catalysts to increase the formation of amorphous carbon by increasing the carbon diffusion barrier, aiming to enhance the coking resistance of Ni-based catalysts.

APPLIED CATALYSIS B-ENVIRONMENTAL (2022)

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Article Engineering, Chemical

Remarkable basic-metal oxides promoted confinement catalysts for CO2 reforming

Jing Wang et al.

FUEL (2022)

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Article Chemistry, Applied

Synthesis gas production by dry reforming of methane over Neodymium-modified hydrotalcite-derived nickel catalysts

Xiaoqing Yuan et al.

Summary: Y Neodymium-modified hydrotalcite-derived nickel catalysts with different Nd contents showed varied catalytic properties in the dry reforming of methane reaction, with Ni7.5NdMgAlO catalyst exhibiting the best performance. Proper doping of neodymium can increase the exposure of active sites on the catalyst surface, effectively inhibit coke formation, and improve coke resistance.

FUEL PROCESSING TECHNOLOGY (2022)

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Article Chemistry, Physical

Structural effect of Ni/SBA-15 by Zr promoter for H2 production via methane dry reforming

N. Abdullah et al.

Summary: The study found that the optimal loading of Zr on the surface of Ni/SBA-15 catalyst was 1wt%, which can promote catalytic performance and increase the conversion rate of methane dry reforming reaction.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Physical

Highly active and stable Ni dispersed on mesoporous CeO2-Al2O3 catalysts for production of syngas by dry reforming of methane

Andre L. A. Marinho et al.

Summary: Ni-based mesoporous mixed CeO2-Al2O3 oxide catalysts prepared by one pot EISA method show high activity and stability in dry reforming of methane, attributed to the confinement of Ni particles and the inhibition of carbon deposition.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

Role of lattice oxygen in methane activation on Ni-phyllosilicate@Ce1-xZrxO2 core-shell catalyst for methane dry reforming: Zr doping effect, mechanism, and kinetic study

Sonali Das et al.

Summary: Sandwich structured core-shell Ni-Phyllosilicate@Ce1-xZrxO2 catalysts with optimal Zr loading in the Ce1-xZrxO2 shell are found to greatly enhance the intrinsic activity for DRM due to increased lattice oxygen mobility of the ceria-zirconia shell and stronger metal-support interaction with Ni. Involvement of lattice oxygen in methane activation and dissociation contributes to the higher DRM activity of the Zr-doped catalyst with maximum oxygen storage capacity, as inferred from rigorous kinetic and mechanism studies.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Physical

NixAl1O2-δ mesoporous catalysts for dry reforming of methane: The special role of NiAl2O4 spinel phase and its reaction mechanism

Shuangshuang Zhang et al.

Summary: The evolution of the surface NiAl2O4 spinel phase in NixAl1O2-delta mesoporous catalysts synthesized by the citric acid sol-gel method was systematically studied. The constructed Ni-0-NiAl2O4 interfaces and active oxygen species generated by filling oxygen vacancies of NiAl2O4 spinel play important roles in enhancing the stability and resistance to coking and sintering in dry reforming of methane reaction.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Article Chemistry, Multidisciplinary

Investigation of physico-chemical and catalytic properties of the coating layer of silica-coated iron oxide magnetic nanoparticles

A. Lazzarini et al.

Summary: The team synthesized silica-coated iron oxide magnetic nanoparticles as the starting core for easily-recoverable heterogeneous catalysts supports. Various techniques were employed to analyze the features of the synthesized materials, and a oxidation reaction was used to confirm the effectiveness of the silica shield.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2021)

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Article Chemistry, Multidisciplinary

Effects of spatially confined nickel nanoparticles in surface-pretreated hydrophobic SBA-15 for dry reforming of CH4 with CO2

Kyung Soo Park et al.

Summary: Efficient methods for preserving smaller nickel nanoparticles on a highly ordered mesoporous SBA-15 were investigated for high temperature dry reforming of methane with CO2. The spatial confinement of nickel nanoparticles in the SBA-15 channels resulted in suppressed thermal aggregation, less coke deposition, and higher catalytic activity. A surface-pretreated SBA-15 with two-step treatment showed a higher dispersion of stabilized nickel nanoparticles in the ordered mesoporous inner channels.

JOURNAL OF CO2 UTILIZATION (2021)

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Article Chemistry, Applied

The effect of modifier identity on the performance of Ni-based catalyst supported on γ-Al2O3 in dry reforming of methane

Ahmed Sadeq Al-Fatesh et al.

CATALYSIS TODAY (2020)

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Article Chemistry, Physical

Influence of reduction temperature on Ni particle size and catalytic performance of Ni/Mg(Al)O catalyst for CO2 reforming of CH4

Yingying Zhan et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Physical

Enhancing CexZr1-xO2 Activity for Methane Dry Reforming Using Subsurface Ni Dopants

Behnam Safavinia et al.

ACS CATALYSIS (2020)

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Article Chemistry, Physical

Synergy Effects of Cobalt Oxides on Ni/Co-Embedded Al2O3 for Hydrogen-Rich Syngas Production by Steam Reforming of Propane

Kyung Soo Park et al.

CATALYSTS (2020)

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Article Chemistry, Physical

Promotional effects of Cu and Zn in hydrotalcite-derived methane tri-reforming catalyst

Rohit Kumar et al.

APPLIED SURFACE SCIENCE (2020)

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Article Engineering, Chemical

One-Step Synthesis of Highly Active and Stable Ni-ZrOx for Dry Reforming of Methane

Ye Wang et al.

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH (2020)

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Article Chemistry, Physical

Production of hydrogen by methane dry reforming: A study on the effect of cerium and lanthanum on Ni/MgAl2O4 catalyst performance

E. Akiki et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Physical

Effect of surface properties controlled by Ce addition on CO2 methanation over Ni/Ce/Al2O3 catalyst

Min-Jae Kim et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Article Chemistry, Applied

The role of Zr in NiZrAl oxides catalyst and the evaluation on steam reforming of glycerol for hydrogen product

Zhao Yan et al.

CATALYSIS TODAY (2019)

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Review Chemistry, Applied

A review on dry reforming of methane in aspect of catalytic properties

Won-Jun Jang et al.

CATALYSIS TODAY (2019)

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Article Engineering, Environmental

Effect of oxide additives on the hydrotalcite derived Ni catalysts for CO2 reforming of methane

Juntian Niu et al.

CHEMICAL ENGINEERING JOURNAL (2019)

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Article Chemistry, Physical

Insight into the effects of the oxygen species over Ni/ZrO2 catalyst surface on methane reforming with carbon dioxide

Meng Zhang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Physical

The importance of inner cavity space within Ni@SiO2 nanocapsule catalysts for excellent coking resistance in the high-space-velocity dry reforming of methane

Changzhen Wang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Physical

Catalysts in Coronas: A Surface Spatial Confinement Strategy for High-Performance Catalysts in Methane Dry Reforming

Honggen Peng et al.

ACS CATALYSIS (2019)

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Article Chemistry, Physical

Methane dry reforming over boron nitride interface-confined and LDHs-derived Ni catalysts

Kankan Bu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Thermodynamics

Hydrogen production through steam reforming of toluene over Ce, Zr or Fe promoted Ni-Mg-Al hydrotalcite-derived catalysts at low temperature

Fan Zhou et al.

ENERGY CONVERSION AND MANAGEMENT (2019)

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Article Chemistry, Physical

Sandwiched SiO2@Ni@ZrO2 as a coke resistant nanocatalyst for dry reforming of methane

Jian Dou et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Multidisciplinary

Biogas reforming on hydrotalcite-derived Ni-Mg-Al catalysts: the effect of Ni loading and Ce promotion

Dori Yosef Kalai et al.

JOURNAL OF CO2 UTILIZATION (2019)

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Article Chemistry, Physical

Ordered mesoporous Ni/La2O3 catalysts with interfacial synergism towards CO2 activation in dry reforming of methane

Kang Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

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Article Chemistry, Physical

Adjusted interactions of nickel nanoparticles with cobalt-modified MgAl2O4-SiC for an enhanced catalytic stability during steam reforming of propane

Kyung Soo Park et al.

APPLIED CATALYSIS A-GENERAL (2018)

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Article Chemistry, Physical

Promotion effect of zirconia on Mg(Ni,Al)O mixed oxides derived from hydrotalcites in CO2 methane reforming

Radoslaw Debek et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Silica-Ceria sandwiched Ni core-shell catalyst for low temperature dry reforming of biogas: Coke resistance and mechanistic insights

S. Das et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Core-shell nickel catalysts for the steam reforming of acetic acid

Jianglong Pu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Structure and surface properties of ceria-modified Ni-based catalysts for hydrogen production

S. Damyanova et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Excess-methane dry and oxidative reforming on Ni-containing hydrotalcite-derived catalysts for biogas upgrading into synthesis gas

Armando Izquierdo-Colorado et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Review Green & Sustainable Science & Technology

Catalyst design for dry reforming of methane: Analysis review

Nicolas Abdel Karim Aramouni et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2018)

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Article Chemistry, Physical

NiCo@SiO2 core-shell catalyst with high activity and long lifetime for CO2 conversion through DRM reaction

Yu Zhao et al.

NANO ENERGY (2018)

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Article Chemistry, Multidisciplinary

Effect of the addition of Ce and Zr over a flower-like NiO-MgO (111) solid solution for CO2 reforming of methane

Yao Lu et al.

JOURNAL OF CO2 UTILIZATION (2018)

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Article Chemistry, Physical

Effect of alloy composition on catalytic performance and coke-resistance property of Ni-Cu/Mg(Al)O catalysts for dry reforming of methane

Kai Song et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

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Article Chemistry, Physical

Biogas dry reforming for syngas production on La promoted hydrotalcite-derived Ni catalysts

Dori Yosef Kalai et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2018)

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Article Chemistry, Multidisciplinary

Design of Ni-ZrO2@SiO2 catalyst with ultra-high sintering and coking resistance for dry reforming of methane to prepare syngas

Wenming Liu et al.

JOURNAL OF CO2 UTILIZATION (2018)

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Article Engineering, Environmental

Effects of cerium and lanthanum on Ni-based catalysts for CO2 reforming of toluene

Jihane Abou Rached et al.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2018)

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Review Green & Sustainable Science & Technology

Recent advances in dry reforming of methane over Ni-based catalysts

Bawadi Abdullah et al.

JOURNAL OF CLEANER PRODUCTION (2017)

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Article Chemistry, Multidisciplinary

Highly carbon-resistant Ni-Co/SiO2 catalysts derived from phyllosilicates for dry reforming of methane

Zhoufeng Bian et al.

JOURNAL OF CO2 UTILIZATION (2017)

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Article Chemistry, Multidisciplinary

Ni/M-Al2O3 (M=Sm, Ce or Mg) for combined steam and CO2 reforming of CH4 from coke oven gas

A. Rong Kim et al.

JOURNAL OF CO2 UTILIZATION (2017)

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Article Chemistry, Multidisciplinary

Preparation and characterization of ultrasound-assisted co-precipitated nanocrystalline La-, Ce-, Zr -promoted Ni-Al2O3 catalysts for dry reforming reaction

Farnaz Rahbar Shamskar et al.

JOURNAL OF CO2 UTILIZATION (2017)

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Article Chemistry, Physical

Ni/CeO2 based catalysts as oxygen vectors for the chemical looping dry reforming of methane for syngas production

Axel Loefberg et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Applied

Steam reforming of ethanol over cerium-promoted Ni-Mg-Al hydrotalcite catalysts

Sujoy Bepari et al.

CATALYSIS TODAY (2017)

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Article Chemistry, Applied

Hydrotalcites derived catalysts for syngas production from biogas reforming: Effect of nickel and cerium load

Ananda Vallezi Paladino Lino et al.

CATALYSIS TODAY (2017)

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Article Chemistry, Physical

Uncoupling the size and support effects of Ni catalysIs for dry reforming of methane

Joung Woo Han et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Physical

Highly active and stable alumina supported nickel nanoparticle catalysts for dry reforming of methane

Zeyu Shang et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Physical

Ordered mesoporous one-pot synthesized Ni-Mg(Ca)-Al2O3 as effective and remarkably stable catalysts for combined steam and dry reforming of methane (CSDRM)

Karam Jabbour et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2017)

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Article Chemistry, Physical

Catalyst development for steam reforming of methane and model biogas at low temperature

Sofia D. Angeli et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Article Chemistry, Physical

Highly carbon resistant multicore-shell catalyst derived from Ni-Mg phyllosilicate nanotubes@silica for dry reforming of methane

Zhoufeng Bian et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2016)

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Article Chemistry, Physical

Intrinsic reactivity of Ni, Pd and Pt surfaces in dry reforming and competitive reactions: Insights from first principles calculations and microkinetic modeling simulations

Lucas Foppa et al.

JOURNAL OF CATALYSIS (2016)

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Article Chemistry, Multidisciplinary

Facile synthesis of Ni/SiO2 catalyst by sequential hydrogen/air treatment: A superior anti-coking catalyst for dry reforming of methane

X. Y. Gao et al.

JOURNAL OF CO2 UTILIZATION (2016)

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Article Chemistry, Physical

Ni/CeO2-Al2O3 catalysts for the dry reforming of methane: The effect of CeAlO3 content and nickel crystallite size on catalytic activity and coke resistance

Igor Luisetto et al.

APPLIED CATALYSIS A-GENERAL (2015)

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Article Chemistry, Physical

Bi-functional hydrotalcite-derived NiO-CaO-Al2O3 catalysts for steam reforming of biomass and/or tar model compound at low steam-to-carbon conditions

J. Ashok et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2015)

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Article Engineering, Environmental

Combined steam and CO2 reforming of CH4 using coke oven gas on nickel-based catalyst: Effects of organic acids to nickel dispersion and activity

Hye Yong Lee et al.

CHEMICAL ENGINEERING JOURNAL (2015)

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Article Energy & Fuels

Carbon dioxide reforming of methane over Ni catalysts prepared from Ni-Mg-Al layered double hydroxides: Influence of Ni loadings

Xingyi Lin et al.

FUEL (2015)

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Review Green & Sustainable Science & Technology

Dry reforming of methane: Influence of process parameters-A review

Muhammad Usman et al.

RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2015)

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Article Biotechnology & Applied Microbiology

Catalytic bi-reforming of methane: from greenhouse gases to syngas

Nitin Kumar et al.

CURRENT OPINION IN CHEMICAL ENGINEERING (2015)

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Review Chemistry, Multidisciplinary

A review of dry (CO2) reforming of methane over noble metal catalysts

Devendra Pakhare et al.

CHEMICAL SOCIETY REVIEWS (2014)

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Article Chemistry, Multidisciplinary

Highly Coke-Resistant Ni Nanoparticle Catalysts with Minimal Sintering in Dry Reforming of Methane

Joung Woo Han et al.

CHEMSUSCHEM (2014)

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Article Environmental Sciences

Key factors for assessing climate benefits of natural gas versus coal electricity generation

Xiaochun Zhang et al.

ENVIRONMENTAL RESEARCH LETTERS (2014)

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Article Chemistry, Physical

Preparation of Ni-Cu/Mg/Al catalysts from hydrotalcite-like compounds for hydrogen production by steam reforming of biomass tar

Dalin Li et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2014)

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Article Chemistry, Physical

Bimetallic Ni-Cu catalyst supported on CeO2 for high-temperature water-gas shift reaction: Methane suppression via enhanced CO adsorption

E. T. Saw et al.

JOURNAL OF CATALYSIS (2014)

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Article Chemistry, Physical

Yolk-Satellite-Shell Structured Ni-Yolk@Ni@SiO2 Nanocomposite: Superb Catalyst toward Methane CO2 Reforming Reaction

Ziwei Li et al.

ACS CATALYSIS (2014)

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Article Chemistry, Physical

Ni-Fe catalysts derived from hydrotalcite-like precursors for hydrogen production by ethanol steam reforming

Sonia Abello et al.

APPLIED CATALYSIS A-GENERAL (2013)

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Article Chemistry, Physical

High carbon-resistance Ni/CeAlO3-Al2O3 catalyst for CH4/CO2 reforming

Wei Chen et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2013)

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Article Chemistry, Physical

Steam reforming of toluene as a biomass tar model compound over CeO2 promoted Ni/CaO-Al2O3 catalytic systems

J. Ashok et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2013)

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Article Chemistry, Multidisciplinary

Bi-reforming of Methane from Any Source with Steam and Carbon Dioxide Exclusively to Metgas (CO-2H2) for Methanol and Hydrocarbon Synthesis

George A. Olah et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Article Chemistry, Applied

Ni-Co/Mg-Al catalyst derived from hydrotalcite-like compound prepared by plasma for dry reforming of methane

Huali Long et al.

JOURNAL OF ENERGY CHEMISTRY (2013)

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Article Chemistry, Physical

Stable low-temperature dry reforming of methane over mesoporous La2O3-ZrO2 supported Ni catalyst

Sergey Sokolov et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2012)

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Article Chemistry, Physical

Acido-basic and catalytic properties of transition-metal containing Mg-Al hydrotalcites and their corresponding mixed oxides

Octavian Dumitru Pavel et al.

APPLIED CLAY SCIENCE (2012)

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Article Chemistry, Physical

Steam reforming of tar from pyrolysis of biomass over Ni/Mg/Al catalysts prepared from hydrotalcite-like precursors

Dalin Li et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2011)

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Article Chemistry, Applied

Dry reforming of methane over LnFe0.7Ni0.3O3-δ perovskites: Influence of Ln nature

L. Kapokova et al.

CATALYSIS TODAY (2011)

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Article Chemistry, Applied

Thermodynamic analysis of carbon dioxide reforming of methane in view of solid carbon formation

M. Khoshtinat Nikoo et al.

FUEL PROCESSING TECHNOLOGY (2011)

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Article Chemistry, Physical

Dry reforming of methane over LaNi1-yByO3 +/-delta(B=Mg, Co) perovskites used as catalyst precursor

German Sierra Gallego et al.

APPLIED CATALYSIS A-GENERAL (2008)

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Article Chemistry, Physical

Highly monodisperse zirconia-coated silica spheres and zirconia/silica hollow spheres with remarkable textural properties

Pablo M. Arnal et al.

CHEMISTRY OF MATERIALS (2006)

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Article Chemistry, Applied

Four challenges for nickel steam-reforming catalysts

J Sehested

CATALYSIS TODAY (2006)

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Article Chemistry, Physical

Structural requirements and reaction pathways in condensation reactions of alcohols an MgyAlOx catalysts

JI Di Cosimo et al.

JOURNAL OF CATALYSIS (2000)

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Roles of metal oxide overlayers on hydrotalcite-structured Ni-MgAlOx for dry reforming of CH4 with CO2

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