期刊
FUEL
卷 347, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2023.128331
关键词
Gas -water relative permeability; Water vapor adsorption; Crushed -rock; Shales; Relative permeability hysteresis
Relative permeability controls fluid flow through rocks, with applications to hydrocarbon production, geologic carbon and energy storage. However, significant challenges are associated with the measurement of relative permeability for rocks with matrix permeability in the microdarcy to nanodarcy range. This study proposes an integrated experimental and modeling approach for gas relative permeability evaluation using crushed-rock samples and demonstrates the feasibility of determining gas-liquid relative permeability for ultra-low-permeability reservoir samples.
Relative permeability controls fluid flow through rocks, with applications to hydrocarbon production, geologic carbon and energy storage. However, significant challenges are associated with the measurement of relative permeability for rocks with matrix permeability in the microdarcy to nanodarcy range. The primary objectives of this study are therefore to 1) propose an integrated experimental and modeling approach for gas relative permeability (krg) evaluation using crushed-rock samples and 2) perform a proof-of-concept study to demonstrate that gas-liquid relative permeability can be determined for ultra-low-permeability (unconventional) reservoir samples that have been crushed to certain grain sizes (20-35 mesh size). In this study, the water vapor ad-/desorption technique was employed to provide a wide range of water saturations (Sw). The evolution of water distribution in the shale matrix with a change in Sw was investigated by using a modified low-pressure adsorption (LPA) technique. A recently-developed numerical model was modified to estimate effective permeability to gas at each saturation level. Four clay-rich shales from the Duvernay (Canadian) and Kyalla (Australian) formations were analyzed. The vapor ad-/desorption technique provided an efficient approach to saturate the studied samples. By changing relative humidity in sealed desiccators using different salt solutions, a maximum Sw of 83% was obtained for organic-matter rich samples, and 99% for organic-matter lean shales. As interpreted using the modified LPA technique applied at different saturation levels, water is held in films in mineral-associated macro-/mesopores, and can block access to organic-matter pores through the formation of water clusters, significantly reducing the accessible organic-matter porosity and gas effective permeability. Imbibition krg decreases rapidly and significantly (over 90%) when Sw reaches approximately 0.3-0.4 for samples containing significant amounts of water-sensitive clay minerals (Kyalla #2) and TOC (Duvernay #2). Relative permeability hysteresis occurs for Duvernay #2 and Kyalla #1. Overall, the use of crushed-rock samples (non-matrix/fracture system), and application of the vapor sorption technique, results in a small amount of hysteresis. A laboratory-based method for measuring gas relative permeability of ultra-low-permeability reservoirs using crushed-rock samples is provided for the first time, with important applications to the energy and carbon capture industries.
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