期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 11, 页码 2126-2129出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09245g
关键词
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资金
- National Natural Science Foundation of China [21102119, 21272191]
- Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT)
- NFFTBS [J1310024]
A direct gold-catalyzed 5-endo-dig cycloisomerization of chiral homopropargyl sulfonamides has been developed. A range of enantioenriched 2,3-dihydropyrroles are readily accessed by utilizing this approach. Importantly, this gold-catalyzed cycloisomerization reaction proceeds through an anti-Markovnikov addition by using a catalytic base as the additive, which completely suppresses the undesired dimerization.
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