期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 11, 页码 2056-2059出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc09407g
关键词
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资金
- 973 Programs [2014CB239303]
- NSFC [21273035, 21373048]
- Specialized Research Fund for the Doctoral Program of Higher Education [20123514110002]
- Award Program for Minjiang Scholar Professorship
Ti-substituted NH2-Uio-66(Zr/Ti) prepared by using a post-synthetic exchange (PSE) method showed enhanced photocatalytic performance for both CO2 reduction and hydrogen evolution under visible light. Density functional theory (DFT) calculations and electron spin resonance (ESR) results reveal that the introduced Ti substituent acts as a mediator to facilitate electron transfer, which results in enhanced performance.
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