期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 38, 页码 8054-8057出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc00685f
关键词
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资金
- National Natural Science Foundation of China [21202059]
- China Postdoctoral Science Foundation [2013M541287]
- Jilin Province Science & Technology Development Program [20100538, 20110436, 201215033]
The first enantioselective aza-Friedel-Crafts reaction between pyrroles and enamides has been achieved by using a novel H-8-BINOL-type imidodiphosphoric acid catalyst. This methodology was also applied to the highly enantioselective aza-Friedel-Crafts reaction between pyrroles and imines. The catalyst loadings in these two reactions are low (0.3-2 mol%). Both processes are amenable to gram scales.
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