4.2 Article

Lanthanide complexes based on ethyl 2-hydroxymethylidene-3-oxobutanoate

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MENDELEEV COMMUNICATIONS
卷 26, 期 1, 页码 54-56

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ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2016.01.021

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  1. Presidium of the Ural Branch of the Russian Academy of Sciences [15-21-3-7]
  2. State Program for Supporting of Leading Scientific Schools of the Russian Federation [NSh-8922.2016.3]

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The reaction of europium(III) or terbium(III) chlorides with ethyl 2-hydroxymethylidene-3-oxobutanoate in the presence of 2,2'-bipyridine (2,2'-bipy) resulted in the luminescent complexes [LnL(3)]center dot 2,2'-bipy (L = ethyl 2-hydroxymethylidene-3-oxobutanoate, Ln = Tb-III or Eu-III), whose molecular structure has been determined by X-ray analysis.

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