☆ 4.5 Review

Palladium-Catalyzed Enantioselective Hydrofunctionalization of Alkenes: Recent Advances

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2023)

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Summary: We report a transient directing group (TDG) strategy for site-selective palladium-catalyzed reductive Heck-type hydroalkenylation and hydroalkynylation of alkenylaldehydes using alkenyl and alkynyl bromides. This strategy allows for the construction of a stereocenter at the delta-position with respect to the aldehyde. Computational studies reveal the beneficial roles of rigid TDGs, such as L-tert-leucine, in promoting TDG binding and inducing high levels of enantioselectivity in alkene insertion.

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Asymmetric Hydrosilylation of β-Silyl Styrenes Catalyzed by a Chiral Palladium Complex

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Hydrovinylation Reactions - Atom-Economic Transformations with Steadily Increasing Synthetic Potential

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Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: Recent developments and trends

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Bidentate planar chiral η6-arene tricarbonyl chromium(0) complexes:: ligands for catalytic asymmetric alkene hydrosilylation

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First examples of enantioselective palladium-catalyzed thiocarbonylation of prochiral 1,3-conjugated dienes with thiols and carbon monoxide:: Efficient synthesis of optically active β,γ-unsaturated thiol esters

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Asymmetric hydrosilylation of styrenes catalyzed by palladium-MOP complexes: Ligand modification and mechanistic studies

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Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines

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