期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202300456
关键词
difunctionalization of alkynes; one-pot; transition-metal-free; C-C triple bond oxidation; synthesis
A transition-metal-free one-pot procedure has been developed for the difunctionalization of alkynes by C-C triple bond oxidation and transformation towards chromone derivatives. This method involves cascade reactions for carbonylation of alkynes, base-promoted C-C & sigma;-bond cleavage, and intramolecular cyclization. It provides an efficient protocol for the synthesis of polysubstituted chromones from readily available starting materials.
A transition-metal-free one-pot procedure for the difunctionalization of alkynes by C-C triple bond oxidation and transformation towards chromone derivatives has been developed. It involves cascade reactions for carbonylation of alkynes, base-promoted C-C & sigma;-bond cleavage, and intramolecular cyclization. This procedure provides an efficient protocol for the synthesis of polysubstituted chromones from readily available starting materials.
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