4.7 Article

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

期刊

CHEMICAL COMMUNICATIONS
卷 51, 期 1, 页码 101-103

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc08312a

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资金

  1. EPSRC (UK) [EP/K039547/1]
  2. University of Manchester
  3. Royal Society for a Wolfson research merit award
  4. EPSRC [EP/K039547/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [EP/K039547/1, 1329386] Funding Source: researchfish

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We report the first near-linear bis(amide) 4f-block compound and show that this novel structure, if implemented with dysprosium(III), would have unprecedented single molecule magnet (SMM) properties with an energy barrier, U-eff, for reorientation of magnetization of 1800 cm(-1).

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