☆ 4.5 Article

Reactivity Studies of Cyclic Alkyl(Amino) Carbene (cAAC)-Supported Phosphinidenide with AuCl

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2023)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Inorganic & Nuclear

From Au11 to Au13: Tailored Synthesis of Superatomic Di-NHC/PPh3-Stabilized Molecular Gold Nanoclusters

Matteo Bevilacqua et al.

Summary: We report a new method for synthesizing phosphine (PR3) and di-N-heterocyclic carbene (di-NHC) ligand stabilized molecular gold nanoclusters (AuNCs). The reaction of di-NHC gold(I) complexes with [Au11(PPh3)8Cl2]Cl clusters results in the formation of three new classes of AuNCs through a controllable reaction sequence. The electronic and steric properties of the di-NHC ligand affect the product distribution, leading to the isolation and characterization of different clusters. One of the characterized clusters shows strong emission in solution.

INORGANIC CHEMISTRY (2023)

添加到收藏夹

Review Biochemical Research Methods

Gold Nanoclusters: Imaging, Therapy, and Theranostic Roles in Biomedical Applications

Sanne M. van de Looij et al.

Summary: Over the past two decades, atomic gold nanoclusters have shown promising applications in cancer diagnosis and treatment, with their native luminescent properties and the use of active targeting strategies contributing to their extensive potential in biomedical imaging and therapy.

BIOCONJUGATE CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Physical

Insight Into the Stability and Electronic and Optical Properties of N-Heterocyclic Carbene Analogues of Halogen/Phosphine-Protected Au13 Superatomic Clusters

Jianyu Wei et al.

Summary: This study explores the feasibility of incorporating N-heterocyclic carbenes (NHCs) as part of the protecting-ligand shell in gold nanoclusters (AuNCs). The results show that the substitution of phosphine ligands with NHCs in experimentally characterized AuNCs demonstrates similar electronic structure and stability, but slightly different optical properties. These findings support the obtainment of novel targets for explorative synthesis efforts featuring NHC ligands on medium-sized species based on the recurrent Au-13 icosahedral core.

JOURNAL OF PHYSICAL CHEMISTRY A (2022)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Carbene-Anchored Boryl- and Stibanyl-Phosphaalkenes as Precursors for Bis-Phosphaalkenyl Dichlorogermane and Mixed- Valence AgI/AgII Phosphinidenide

Ekta Nag et al.

Summary: By synthesizing and characterizing a series of novel cAAC-anchored boryl-and stibanyl-phosphaalkenes, it has been found that these compounds exhibit redox noninnocent behavior in solution, while revealing their molecular structures and properties.

INORGANIC CHEMISTRY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Isolation of Homo-/Mixed-Valence Ag12, Ag29, and Ag8 Clusters Stabilized by Cyclic Alkyl(amino) Carbene-Anchored Monoanionic Phosphorus Ligand

Ekta Nag et al.

Summary: This study reports on the synthesis and isolation of silver nanoclusters with Ag12Cl3, Ag-29, and Ag-8 cores for the first time. It was found that these clusters exhibit different magnetic and optical properties.

CHEMISTRY-A EUROPEAN JOURNAL (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

NHC-Stabilized Au10 Nanoclusters and Their Conversion to Au25 Nanoclusters

Paul A. Lummis et al.

Summary: The synthesis of a toroidal Au-10 cluster stabilized by N-heterocyclic carbene and halide ligands is described via reduction of NHC-Au-X complexes (X = Cl, Br, I). The halide ligands significantly affect the formation, stability, and conversions of these clusters. The bromide derivative readily converts to a biicosahedral Au-25 cluster at room temperature, while the iodide derivative shows significant formation of Au-25 upon reduction of NHC-Au-I. The isolated bromide derivative of Au-25 cluster exhibits relatively high photoluminescence quantum yield due to the high rigidity enforced by multiple CH-pi interactions.

JACS AU (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Solid-State Isolation of Cyclic Alkyl(Amino) Carbene (cAAC)-Supported Structurally Diverse Alkali Metal-Phosphinidenides

Aditya Kulkarni et al.

Summary: Cyclic alkyl(amino) carbene (cAAC)-supported, structurally diverse alkali metal-phosphinidenides have been synthesized and characterized through NMR studies and X-ray diffraction. The mechanism of electron transfer process was supported by cyclic voltammetry studies and Density Functional Theory calculations. The solid state oligomerization process was found to be largely dependent on the ionic radii of alkali metal ions, steric bulk of cAAC ligands, and solvation/de-solvation/recombination of the dimeric unit.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications

Rodolphe Jazzar et al.

CHEMICAL REVIEWS (2020)

添加到收藏夹

Article Multidisciplinary Sciences

Highly efficient blue organic light-emitting diodes based on carbene-metal-amides

Patrick J. Conaghan et al.

NATURE COMMUNICATIONS (2020)

添加到收藏夹

Article Chemistry, Physical

Mono- versus Bicyclic Carbene Metal Amide Photoemitters: Which Design Leads to the Best Performance?

Florian Chotard et al.

CHEMISTRY OF MATERIALS (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Bisphosphine-Stabilized Gold Nanoclusters with the Crown/Birdcage-Shaped Au11 Cores: Structures and Optical Properties

Ting-Hong Huang et al.

INORGANIC CHEMISTRY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Ligand-protected gold/silver superatoms: current status and emerging trends

Haru Hirai et al.

CHEMICAL SCIENCE (2020)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A new approach to the synthesis of trinuclear gold(I) imidazolate complexes and their silver(I)-induced photoluminescence behavior

Javier Ruiz et al.

DALTON TRANSACTIONS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Low-Valent Group 14 NHC-Stabilized Phosphinidenide ate Complexes and NHC-Stabilized K/P-Clusters

Markus Balmer et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-heterocyclic carbene-functionalized magic-number gold nanoclusters

Mina R. Narouz et al.

NATURE CHEMISTRY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Gold Nanoclusters: Bridging Gold Complexes and Plasmonic Nanoparticles in Photophysical Properties

Meng Zhou et al.

NANOMATERIALS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes

Mina R. Narouz et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis, Structure, and Reactivity of an NHC Silyl Gold(I) Complex

Maximilian Joost et al.

ORGANOMETALLICS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Tools for Prescreening the Most Active Sites on Ir and Rh Clusters toward C-H Bond Cleavage of Ethane: NBO Charges and Wiberg Bond Indexes

Yingbin Ge et al.

ACS OMEGA (2019)

添加到收藏夹

Article Chemistry, Physical

The intersystem crossing of a cyclic (alkyl)(amino) carbene gold (i) complex

S. Thompson et al.

JOURNAL OF CHEMICAL PHYSICS (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis and characterization of Ag(I) and Au(I) complexes with macrocyclic hybrid amine N-heterocyclic carbene ligands

Taotao Lu et al.

NEW JOURNAL OF CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

A Carbon-Centered Hexagold(I) Cluster Supported by N-Heterocyclic Carbene Ligands

Hitoshi Ube et al.

ORGANOMETALLICS (2018)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

N-Heterocyclic Carbene-Phosphinidene and Carbene-Phosphinidenide Transition Metal Complexes

Marius Peters et al.

INORGANIC CHEMISTRY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

A N-Heterocyclic Carbene-Stabilized Coinage Metal-Chalcogenide Framework with Tunable Optical Properties

Alexander M. Polgar et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Two Structurally Characterized Conformational Isomers with Different C-P Bonds

Sudipta Roy et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper and Gold Cyclic (Alkyl)(amino)carbene Complexes with Sub-Microsecond Photoemissions: Structure and Substituent Effects on Redox and Luminescent Properties

Alexander S. Romanov et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Observation of uniform ligand environments and P-31-Au-197 coupling in phosphine-terminated Au nanoparticles

Lauren E. Marbella et al.

CHEMICAL COMMUNICATIONS (2016)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Aurophilicity in Action: Fine-Tuning the Gold(I)-Gold(I) Distance in the Excited State To Modulate the Emission in a Series of Dinuclear Homoleptic Gold(I)-NHC Complexes

Alexander A. Penney et al.

INORGANIC CHEMISTRY (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidene Complexes of the Coinage Metals

Adinarayana Doddi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Copper(I), silver(I) and gold(I) complexes of N-heterocyclic carbene-phosphinidene

Venkata A. K. Adiraju et al.

DALTON TRANSACTIONS (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Gold(I) and Gold(III) Complexes of Cyclic (Alkyl)(amino)carbenes

Alexander S. Romanov et al.

ORGANOMETALLICS (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Trinuclear Gold Clusters Supported by Cyclic (alkyl)(amino)carbene Ligands: Mimics for Gold Heterogeneous Catalysts

Liqun Jin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Phosphinidyne Transition Metal Complexes

Adinarayana Doddi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Isolation of a Non-Heteroatom-Stabilized Gold-Carbene Complex

Matthias W. Hussong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Formation of Trichlorosilyl-Substituted Carbon-Centered Stable Radicals through the Use of π-Accepting Carbenes

Kartik Chandra Mondal et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

NHC-Mediated Synthesis of an Asymmetric, Cationic Phosphoranide, a Phosphanide, and Coinage-Metal Phosphanido Complexes

Kai Schwedtmann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Chiral heterobimetallic complexes of carbodiphosphoranes and phosphinidene-carbene adducts

Manuel Alcarazo et al.

CHEMICAL COMMUNICATIONS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

NBO 6.0: Natural bond orbital analysis program

Eric D. Glendening et al.

JOURNAL OF COMPUTATIONAL CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of a Trigold Monocation: An Isolobal Analogue of [H3]+

Thomas J. Robilotto et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

添加到收藏夹

Article Chemistry, Multidisciplinary

[{Au(IPr)}(2)(mu-OH)]X Complexes: Synthetic, Structural and Catalytic Studies

Ruben S. Ramon et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

ShelXle: a Qt graphical user interface for SHELXL

Christian B. Huebschle et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2011)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Solid-state P-31 NMR characterisation of phosphinine-stabilised gold nanoparticles and a phosphinine-gold complex

Samith Komath Mallissery et al.

DALTON TRANSACTIONS (2010)

添加到收藏夹

Article Chemistry, Multidisciplinary

Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications

Olivier Back et al.

NATURE CHEMISTRY (2010)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Cyclic (alkyl)(amino)carbene gold(I) complexes: A synthetic and structural investigation

Guido D. Frey et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Quantum mechanical continuum solvation models

J Tomasi et al.

CHEMICAL REVIEWS (2005)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stable cyclic (alkyl) (amino) carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: A quaternary carbon atom makes the difference

V Lavallo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

添加到收藏夹

Article Chemistry, Physical

Natural transition orbitals

RL Martin

JOURNAL OF CHEMICAL PHYSICS (2003)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.