Synergistic influence of vanadium pentoxide-coupled graphitic carbon nitride composite for photocatalytic degradation of organic pollutant: Stability and involved Z-scheme mechanism

The removal of dyes from wastewater by photocatalytic technologies has received substantial attention in recent years. In the present study, novel Z-scheme V2O5/g-C3N4 photocatalytic composites were organized via simple hydrothermal processes and a sequence of several characterization aspects. The degradation results showed that the optimum Z-scheme GVO2 heterostructure composite photocatalysts (PCs) had a better efficiency (90.1%) and an apparent rate (0.0136 min-1) for the methylene blue (MB) aqueous organic dye degradation, which was about 6.18-fold higher than that of pristine GCN catalyst. Meanwhile, the GVO2 heterostructured PCs showed better recycling stability after five consecutive tests. Moreover, the free radical trapping tests established that & BULL;O2 � and h+ species were the prime reactive species in the photocatalytic MB degradation process in the heterostructured PCs. The photocatalytic enhanced activity was primarily recognized as the synergistic interfacial construction of the Z-scheme heterojunctions among V2O5 and GCN, which improved the separation/transfer, lower recombi-nation rate, extended visible-light utilization ability, and enhanced reaction rate. Therefore, the existing study affords a simple tactic for the development of a direct Z-scheme for photocatalytic heterojunction nanomaterials for potential environmental remediation applications.

Automated summary

In this study, novel Z-scheme V2O5/g-C3N4 photocatalytic composites were prepared through simple hydrothermal processes. These composites showed significantly improved efficiency and reaction rate for the degradation of methylene blue compared to pristine GCN catalyst. The enhanced activity was attributed to the synergistic interfacial construction of the Z-scheme heterojunctions among V2O5 and GCN, which improved separation/transfer and enhanced visible-light utilization.