期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 77, 页码 14489-14492出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc06166k
关键词
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资金
- National Basic Research Program of China (973 Program) [2013CB834803, 2012CB821700]
- NSFC [21171113, 91222202, 21171114]
- Department of Education in Guangdong Province
The racemic conglomerate (1P-NH3 + 1M-NH3) and enantioenriched bulk samples (1P-H2O or 1M-NH3) of Co(II) metal-organic frameworks were obtained from achiral precursors under different solvothermal conditions. The bulk homochirality was generated through asymmetrical crystallization in the absence of any chiral additives confirmed by single crystal X-ray diffraction and CD spectroscopy.
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