期刊
CHEMICAL COMMUNICATIONS
卷 51, 期 62, 页码 12431-12434出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc04287a
关键词
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资金
- Spanish Ministry of Economy and Competitiveness (MINECO/FEDER) (CONSOLIDER INGENIO) [CSD2009-0050, CTQ2011-27593, CTQ2012-35665, CTQ2013-42532-P]
- KFUPM-University of Zaragoza research agreement
- Centre of Research Excellence in Petroleum Refining KFUPM
- [DGA/FSE-E07]
A new PCP-type ligand based on an N-heterocyclic olefin (NHO) scaffold has been prepared. The flexibility of this ligand, which is able to adopt facial coordination modes in Ir(I) or meridional in Ir(III) complexes, can be attributed to the dual nature (ylide-olefin) of the NHO scaffold. This results in a rare case of olefin slippage'' that is supported by X-ray crystallography and DFT calculations.
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